期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 469, 期 -, 页码 63-68出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2016.02.020
关键词
CO2 geo-sequestration; Residual trapping; Storage capacity; Wettability; Oil-wet; Oil reservoir
资金
- Australian Federal Government
Residual trapping, a key CO2 geo-storage mechanism during the first decades of a sequestration project, immobilizes micrometre sized CO2 bubbles in the pore network of the rock. This mechanism has been proven to work in clean sandstones and carbonates; however, this mechanism has not been proven for the economically most important storage sites into which CO2 will be initially injected at industrial scale, namely oil reservoirs. The key difference is that oil reservoirs are typically oil-wet or intermediate-wet, and it is clear that associated pore-scale capillary forces are different. And this difference in capillary forces clearly reduces the capillary trapping capacity (residual trapping) as we demonstrate here. For an oil-wet rock (water contact angle theta = 130 degrees) residual CO2 saturation S-CO2,S-r (approximate to 8%)was approximately halved when compared to a strongly water-wet rock (theta = 0 degrees; S-CO2,S-r approximate to 15%). Consequently, residual trapping is less efficient in oil-wet reservoirs. (C) 2016 Elsevier Inc. All rights reserved.
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