期刊
COORDINATION CHEMISTRY REVIEWS
卷 462, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2022.214503
关键词
Pillar[n]arene; Host-guest chemistry; Solid-state complexation; Supramolecular chemistry
资金
- JSPS KAKENHI [JP15H00990, JP17H05148, JP18H04510, JP20H04670, JP19H00909, JP21K20533, JP20K22528, JP21K14611, JP21K14612]
- JST CREST [JPMJCR18R3]
- MEXT World Premier International Research Center Initiative (WPI), Japan
Pillar[n]arenes, a new type of pillar-shaped host molecule, exhibit versatile and unique host-guest behaviors in host-guest chemistry. Solid-state host-guest complexation offers advantages such as cavity-size dependency, efficient complexation, and easy isolation and reuse. This review discusses recent developments in solid-state host-guest complexation using crystalline pillar[n]arenes, networks containing pillar[n]arenes, pillar[n]arene-assembled surfaces, and solid-state organic polymers.
Pillar[n]arenes, which were first reported by our group in 2008, are a new type of pillar-shaped host molecule in host-guest chemistry with versatile and unique host-guest behaviors. Host-guest complexation is mostly investigated in solution systems, where both the host and guest molecules are normally dissolved in solvent. Compared with normal host-guest complexation in solvents, solid-state host-guest complexation can offer the following advantages and characteristics: (i) Cavity-size dependent host- guest complexation, (ii) efficient host-guest complexation, and (iii) easy host-guest complex isolation and solid-state pillar[n]arene reuse. In this review, we discuss the recent development of solid-state host-guest complexation using crystalline pillar[n]arenes, two or three-dimensional networks containing pillar[n]arenes, including hydrogen-bonded organic frameworks (HOFs), and metal-organic frameworks (MOFs), pillar[n]arene-assembled surfaces, and solid-state organic polymers containing pillar[n]arenes. (C)& nbsp;2022 Elsevier B.V. All rights reserved.
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