期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 647, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.colsurfa.2022.129057
关键词
Graphene oxide; Transition metal oxide nanoparticles; Preferential binding; Fluorescence spectroscopy, Hydrodynamic radius; Zeta potential
资金
- Higher Education Commission of Pakistan under National Research Program for Universities [20-3369/RD/HEC/14/978]
This study investigates the interaction between graphene oxide and various transition metal oxide nanoparticles, and finds that CoO nanoparticles have the highest binding affinity with graphene oxide. Understanding the detailed interaction behavior between transition metal oxide nanoparticles and carbon-based materials can improve the applications of transition metal oxide composites and potentially lead to new applications such as sensors for detection.
Graphene oxide being a low-cost material with multiple functionalities and well-known spectroscopic properties is studied for its preferential binding through its functional groups with Fe3O4, CoO, NiO, CuO and ZnO NPs using various techniques, where CoO nanoparticles have shown the highest binding affinity among these metal oxide nanoparticles. Transition metal oxide nanoparticles along with carbon-based materials have been used for various applications, however the interactive behavior of these two classes of materials have never been understood in detail to reveal the functionalities that are important for the binding. This is so far only known about noble metal nanoparticle - graphene oxide hybrids, which are not only expensive but have limited functionalities. This understanding will not only improve the already reported applications of transition metal oxide composites but also potentially realize new applications, e.g., sensors for the detection of various moieties.
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