4.6 Article

Co3Fe7/Mo2C co-embedded in N-codoped porous carbon with accelerated kinetics for OER and HER

出版社

ELSEVIER
DOI: 10.1016/j.colsurfa.2022.128953

关键词

Mo-Co-Fe; NC; Oxygen evolution reaction; Hydrogen evolution reaction; Reaction kinetics

资金

  1. National Natural Science Foundation of China, China [51701001, 61804039, 51802145]
  2. Academic fund-ing projects for Top Talents in Subjects (Majors) of Universities, China [1808085QE126]
  3. Academic funding projects for Top Talents in Subjects (Majors) of Universities, China [1808085QE126]
  4. Natural Science Foundation of Anhui Province, China [gxbjZD31]
  5. Universities Joint Key Laboratory of Photoelectric Detection Science and Technology in Anhui Province, China [1808085QE126]
  6. Provincial Quality Engineering Project of Colleges and Universities in Anhui Province China [2020GDTCZD01]
  7. Collaborative innovation project of colleges and universities in Anhui Province, China [2020jxtd210]
  8. [GXXT-2021-091]

向作者/读者索取更多资源

Multicomponent metal/N-doped porous carbon materials have high efficiency in oxygen evolution and hydrogen evolution reactions, and have broad application prospects in the field of energy storage and conversion.
Multicomponent metal/N-doped porous carbon with controllable structure is considered to be a promising candidates for efficient oxygen evolution and hydrogen evolution reaction. Herein, Mo-Co-Fe-MOF was preapred by a simple hydrothermal method, followed by high-temperature pyrolysis treatment to obtain the Mo-Co-Fe/ NC. Benefit from the advantages of hierarchical structure and multicomponent, the Mo-Co-Fe-1.0/NC shows an overpotential of 257 and 320 mV to achieve the current density of 10 and 100 mA cm-2 for OER in alkaline KOH solution, respectively. In addition, the Mo-Co-Fe-1.0/NC exhibits the accelerated reaction kinetics during HER and OER reactions. The results provide a new perspective for design and preparation as well as kinetic characteristics of efficient OER and HER catalysts, which is expected to be used in the field of energy storage and conversion.

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