4.8 Article

Decomposition of Deep Eutectic Solvent Aids Metals Extraction in Lithium-Ion Batteries Recycling

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Engineering, Environmental

Ionization potential-based design of deep eutectic solvent for recycling of spent lithium ion batteries

Yunhui Hua et al.

Summary: In this study, a simple and universal approach using ionization potential (IP) calculation assisted with cyclic voltammetry test was proposed for selecting organic acid as a reductant in deep eutectic solvent (DES) for recycling of spent lithium ion batteries (LIBs). The reducibility of organic acid was found to have a close relationship with the IP, and organic acids of lower IP were found to be more preferred as reductants. The designed DES from IP calculation was versatile for treating various kinds of spent battery cathodes and capable of multiple uses, reducing secondary chemical waste and pollution.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Cathode Active Material Recycling from Spent Lithium Batteries: A Green (Circular) Approach Based on Deep Eutectic Solvents

Riccardo Morina et al.

Summary: A novel and green proof-of-concept using deep eutectic solvents (DES) has been developed to fully recover valuable metals from various cathode active materials with high efficiency and purity, achieving selective recovery of metals such as Li, Mn, Co, and Ni under milder conditions. The proposed method also allows for simple separation of cathode components and the reuse of leaching solvents for multiple extractions, thus further enhancing process sustainability.

CHEMSUSCHEM (2022)

Review Chemistry, Physical

Recycling of Lithium-Ion Batteries-Current State of the Art, Circular Economy, and Next Generation Recycling

Jonas Neumann et al.

Summary: This paper provides an overview of the current state and future trends in the recycling technology of lithium-ion batteries. The widespread use of lithium-ion batteries in various applications necessitates the development of efficient recycling methods. However, the complexity of these batteries and their varying compositions pose challenges in establishing a robust recycling procedure. The paper discusses current practices and regulations, as well as predictions and approaches for future battery recycling.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Multidisciplinary

Efficient Recovery of Value Metals from Spent Lithium-Ion Batteries by Combining Deep Eutectic Solvents and Coextraction

Kang Wang et al.

Summary: The advancement of the electric vehicle industry has led to increased production of lithium-ion batteries, resulting in a need for effective recycling methods. In this study, a high-efficiency recycling method using deep eutectic solvents was proposed to leach value metals from cathode materials. The recovered metals showed excellent electrochemical performance, demonstrating the potential for sustainable development of spent lithium-ion batteries.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Chemistry, Multidisciplinary

A Novel Deep-Eutectic Solvent with Strong Coordination Ability and Low Viscosity for Efficient Extraction of Valuable Metals from Spent Lithium-Ion Batteries

Shujie Tang et al.

Summary: A novel type of deep-eutectic solvents (DESs) composed of ethylene glycol (EG) and sulfosalicylic acid dihydrate (SAD) was designed for efficient leaching of valuable metals from spent lithium-ion batteries for the first time. By systematically investigating the experimental parameters, high extraction efficiencies of Co and Li from different cathode active materials were achieved. The leaching mechanism involved replacement of Li+ ions in the interlayer of LiCoO2 and coordination of Co3+ ions in the skeleton structure to form soluble complexes, with leaching kinetics following the shrinking core model.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Editorial Material Chemistry, Physical

Lithium-Ion Battery Recycling-Overview of Techniques and Trends

Zachary J. Baum et al.

ACS ENERGY LETTERS (2022)

Review Green & Sustainable Science & Technology

Production, Use and Recycling of Fruit Cultivating Bags in China

Hongguang Yang et al.

Summary: This paper summarizes the key role of preharvest bagging in the growth and development of fruits, mentioning that China is one of the world's major fruit producers and also the country that uses the most fruit cultivating bags. The article also points out the need to pay attention to recycling and reusing waste fruit cultivating bags.

SUSTAINABILITY (2022)

Review Green & Sustainable Science & Technology

Deep Eutectic Solvents: Green Approach for Cathode Recycling of Li-Ion Batteries

Chinmayee Padwal et al.

Summary: The demand for rechargeable lithium-ion batteries (LIBs) in modern electronics and electrification of transportation has led to a significant increase in solid waste. Recycling strategies using deep eutectic solvents (DESs) provide an economical and environmentally friendly solution for recovering metals from spent LIBs. The mechanism and performance of DES in terms of leaching efficiency, time, temperature, and metal recovery rates are discussed. Opportunities for further development of DES for metal recovery in various industries are also outlined.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2022)

Article Electrochemistry

Electrochemical Decomposition of Primary Alcohol Groups in Deep Eutectic Solvents

Nicholas S. Sinclair et al.

Summary: This study investigates the electrochemical decomposition of ethylene glycol/sodium chloride electrolyte and deep eutectic solvent, revealing a hydrogen production reaction under cathodic conditions and an aldehyde reaction under anodic conditions. The research also shows that a tertiary alcohol only DES has increased stability compared to primary alcohol electrolytes.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Engineering, Environmental

Selective recovery of cobalt from mixed lithium ion battery wastes using deep eutectic solvent

Pier Giorgio Schiavi et al.

Summary: This study presents a method for selectively recovering cobalt from mixed lithium-ion battery electrode materials using a green deep eutectic solvent (DES). The optimized solvent extraction procedure efficiently recovers cobalt as cobalt oxalate, which is then used to produce high-performance lithium cobalt oxide cathode material. The demonstrated selectivity of the leaching method and the ability to reuse the residual DES solution offer a green recycling alternative for reintroducing strategic materials into the lithium-ion battery production chain.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

A Unified Method for the Recovery of Metals from Chalcogenides

Francesca Bevan et al.

Summary: Metal chalcogenides can be electrochemically solubilized from solid powders in deep eutectic solvents, releasing metal ions unaffected by the type of chalcogenide present in the initial compound. These metal ions maintain the same speciation as from dissolution of chloride salts, allowing for recovery of metals from mixtures of chalcogenides. The chalcogenides form a mixture of oxyanions in the + IV and + VI oxidation states, which can be separated via standard processes.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Materials Science, Multidisciplinary

Use of Microwave-Assisted Deep Eutectic Solvents to Recycle Lithium Manganese Oxide from Li-Ion Batteries

Zhiwen Xu et al.

Summary: The study found that microwave-assisted deep-eutectic solvent treatment is highly efficient for recycling lithium manganese oxide from spent Li-ion batteries, greatly decreasing leaching time and increasing leaching efficiency.
Article Chemistry, Multidisciplinary

Significant Improvement in Dissolving Lithium-Ion Battery Cathodes Using Novel Deep Eutectic Solvents at Low Temperature

Yu Chen et al.

Summary: A novel deep eutectic solvent based on poly(ethylene glycol) 200 and p-toluenesulfonic acid monohydrate has been designed for the efficient dissolution of lithium cobalt oxide (LCO). The dissolution efficiency is nearly 100% at 100 degrees C within 24 hours, surpassing previous reports. The interaction between the deep eutectic solvent and LCO is found to be a physical process, providing a new strategy for the mild and efficient dissolution of LCO using inexpensive and environmentally friendly solvents.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Chemistry, Multidisciplinary

Electrochemical oxidation as alternative for dissolution of metal oxides in deep eutectic solvents

Ioanna M. Pateli et al.

GREEN CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

The effect of pH and hydrogen bond donor on the dissolution of metal oxides in deep eutectic solvents

Ioanna M. Pateli et al.

GREEN CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

A novel method for screening deep eutectic solvent to recycle the cathode of Li-ion batteries

Shubin Wang et al.

GREEN CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Degradation of Deep-Eutectic Solvents Based on Choline Chloride and Carboxylic Acids

Nerea Rodriguez Rodriguez et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Energy & Fuels

Deep eutectic solvents for cathode recycling of Li-ion batteries

Mai K. Tran et al.

NATURE ENERGY (2019)

Article Chemistry, Physical

Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis

Noemi Delgado-Mellado et al.

JOURNAL OF MOLECULAR LIQUIDS (2018)

Review Chemistry, Physical

Electrodeposition in Ionic Liquids

Qinqin Zhang et al.

CHEMPHYSCHEM (2016)

Review Chemistry, Multidisciplinary

Superoxide Ion: Generation and Chemical Implications

Maan Hayyan et al.

CHEMICAL REVIEWS (2016)

Article Chemistry, Inorganic & Nuclear

EXAFS Study into the Speciation of Metal Salts Dissolved in Ionic Liquids and Deep Eutectic Solvents

Jennifer M. Hartley et al.

INORGANIC CHEMISTRY (2014)

Article Physics, Condensed Matter

Symmetric supercapacitor based on partially exfoliated and reduced graphite oxide in neutral aqueous electrolyte

S. Shivakumara et al.

SOLID STATE COMMUNICATIONS (2014)

Article Chemistry, Multidisciplinary

Electrochemical decomposition of choline chloride based ionic liquid analogues

Kurt Haerens et al.

GREEN CHEMISTRY (2009)

Article Nanoscience & Nanotechnology

Structural engineering of nanoporous anodic aluminium oxide by pulse anodization of aluminium

Woo Lee et al.

NATURE NANOTECHNOLOGY (2008)

Article Electrochemistry

Unusual anodic behaviour of chloride ion in 1-butyl-3-methylimidazolium hexafluorophosphate

HJ Sun et al.

ELECTROCHEMISTRY COMMUNICATIONS (2005)