4.8 Article

In-Situ Anchoring Pb-Free Cs3Bi2Br9@BiOBr Quantum Dots on NHx-Rich Silica with Enhanced Blue Emission and Satisfactory Stability for Photocatalytic Toluene Oxidation

期刊

CHEMSUSCHEM
卷 15, 期 16, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202200793

关键词

blue emission; NHx-rich monodisperse silica; Pb-free perovskite; photocatalytic oxidation of toluene; quantum dots

资金

  1. National Natural Science Foundation of China [21475021, 21427807, 21777096]
  2. Transformation Program of Scientific and Technological Achievements of Jiangsu Province [BA2020060]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions

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In this study, anchored Pb-free Cs3Bi2Br9@BiOBr perovskite quantum dots/A-SiO2 composites were developed, showing improved blue emission performance and good stability. These composites were successfully employed as photocatalysts for the oxidation of toluene, demonstrating high conversion rates and selectivity.
All-inorganic metal halide perovskite quantum dots (QDs) have attracted attention from researchers with their fascinating optoelectronic properties. However, blue-emitting perovskite QDs typically have low photoluminescence quantum yield (PLQY). For potential commercial applications, it is preferable to replace Pb with an element having low toxicity. Here, Pb-free Cs3Bi2Br9@BiOBr perovskite QDs were anchored on the surface of NHx-rich monodisperse silica (A-SiO2) via N-Bi chemical bonding to isolate QDs from each other, thus enhancing efficient surface passivation and suppressing optical decay. Compared to unanchored QDs, Cs3Bi2Br9@BiOBr QDs/A-SiO2 composites exhibited significantly enhanced blue emission performance, the PLQY of which increased from 16.62 % to 77.26 %, in addition to good water and environmental stability. Finally, the novel composites as photocatalysts were used to drive the oxidation of toluene, a template reaction of C(sp(3))-H bond activation and demonstrated astonishing conversion rates (4317 mu mol g(-1) h(-1)) with high selectivity (around 87 %).

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