期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 28, 期 55, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202201085
关键词
alkali metal aluminates; dihydropyridine; heterobimetallic complexes; hydride; London dispersion forces
资金
- Leverhulme Trust [RPG-2019-264]
- EPSRC [EP/K000586/1]
A series of unique aluminates have been synthesized, and it was found that the alkali metal has a significant influence on their properties. Theoretical calculations showed that dispersion forces have a greater impact on stability than electrostatic forces.
A series of group 1 hydrocarbon-soluble donor free aluminates [AM((BuDHP)-Bu-t)(TMP)Al(Bu-i)(2)] (AM=Li, Na, K, Rb) have been synthesised by combining an alkali metal dihydropyridyl unit [(2-(BuC5H5N)-Bu-t)AM)] containing a surrogate hydride (sp(3) C-H) with [(Bu-i)(2)Al(TMP)]. These aluminates have been characterised by X-ray crystallography and NMR spectroscopy. While the lithium aluminate forms a monomer, the heavier alkali metal aluminates exist as polymeric chains propagated by non-covalent interactions between the alkali metal cations and the alkyldihydropyridyl units. Solvates [(THF)Li-((BuDHP)-Bu-t)(TMP)Al(Bu-i)(2)] and [(TMEDA)Na((BuDHP)-Bu-t)(TMP)Al(Bu-i)(2)] have also been crystallographically characterised. Theoretical calculations show how the dispersion forces tend to increase on moving from Li to Rb, as opposed to the electrostatic forces of stabilization, which are orders of magnitude more significant. Having unique structural features, these bimetallic compounds can be considered as starting points for exploring unique reactivity trends as alkali-metal-aluminium hydride surrog[ATES].
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据