期刊
CHEMICAL ENGINEERING JOURNAL
卷 441, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2022.135951
关键词
Squalene; Palladium; Catalytic hydrogenation; Carbon nanotube support; Structured reactors; Seamless scale-up
资金
- region Auvergne-Rhone-Alpes through the 20 th FUI [15 021131 01 - CNR006]
- Agence Nationale de la Recherche (ANR project) [ANR-19]
A process intensification study for the full hydrogenation of bio-derived platform molecule squalene (SQE) into squalane (SQA) using commercial heterogeneous Pd catalysts and Pd supported on carbon nanotubes (CNT) is reported. The study found that Pd/CNT catalyst showed improved catalytic activity for the hydrogenation reaction, but the scalability and operability of the stirred reactor were limited due to the exothermic nature of the reaction. The implementation of the Pd/CNT catalyst in a flow reactor coated on metallic open cell foams allowed for efficient and scalable production of SQA.
A process intensification study for the full hydrogenation of bio-derived platform molecule squalene (SQE) into squalane (SQA), using commercial heterogeneous Pd catalysts and Pd supported on carbon nanotubes (CNT) is reported. Pd/CNT shows a substantial improvement of the catalytic activity for the total hydrogenation of SQE into SQA thanks to cooperativities between Pd nanoparticles and single atoms simultaneously present on the CNT. However, the stirred reactor's productivity, scalability, and operability are limited by the exothermicity of the reaction (Delta rH = - 765 kJ.mol-1). The implementation of the Pd/CNT catalyst in flow was then studied after coating this catalyst on metallic open cell foams. Using the foam-based milli-reactor's characteristics, including high mass and heat transfer rates and safety, fully reduced SQA (>99 %) was obtained at 180 degrees C and 30 bar of H2 for a contact time of 1.45 min with a space-time yield of 68 molSQA.molPd- 1.min- 1. Finally, a scale-up strategy (7 fold) was successfully attempted in a commercially available pilot-scale reactor that meets further seamless scaleup requirements. A production capacity of 2 kg per day using a commercial intensified reactor with a reacting volume of 43.2 mL was obtained under mild conditions (120 degrees C and 30 bar of H2).
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