Enhanced electromagnetic wave absorption properties of PDCs-SiCN(Ni) fibers by in-situ formed CNTs and Ni2Si

By utilizing polymer-derived ceramics (PDCs) method and electrospinning technology, SiCN(Ni) fibers with 1 wt % nickel content at different calcination temperatures (1000-1300 degrees C) were synthesized. The properties of PDCsSiCN(Ni) fibers were tested by XRD, SEM, TEM, Raman spectroscopy, XPS and vector network analyzer. The results showed that the addition of nickel acetylacetonate (NA) promoted the in-situ formation of CNTs and Ni2Si at high temperatures, which could adjust the impedance matching performance and improve the electromagnetic wave (EMW) absorption properties. The minimum reflection loss (RL) of SiCN(Ni) fibers was -47.55 dB (4.2 mm), and the effective absorption band (EAB, RL <= -10 dB) was 3.6 GHz (14.4-18 GHz) under the ultra-thin thickness of 1.24 mm.

Automated summary

SiCN(Ni) fibers with 1 wt % nickel content were synthesized using polymer-derived ceramics method and electrospinning technology. The addition of nickel promoted the formation of CNTs and Ni2Si, improving the impedance matching performance and electromagnetic wave absorption properties. The fabricated fibers showed low reflection loss and wide effective absorption bandwidth.