4.7 Article

High-purity cellulose production from birch wood by γ-valerolactone/water fractionation and IONCELL-P process

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CARBOHYDRATE POLYMERS
卷 288, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2022.119364

关键词

Organosolv process; Dissolving pulp; Cellulose; GVL

资金

  1. Academy of Finland's Flagship Programme [318890, 318891]

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This study presents an environmentally friendly method to produce high-purity cellulose from birch wood using GVL and ionic liquids. The method resulted in a pure dissolving pulp suitable for various applications.
This study presents an environmentally friendly process to produce high-purity cellulose (dissolving pulp) from birch wood by combining gamma-valerolactone (GVL)/water fractionation and ionic liquid treatment of pulp, IONCELL-P (IP). A paper grade pulp was produced from optimal GVL cook with a similar composition to birch kraft pulp and was bleached with ECF sequence before the hemicelluloses were removed using the IONCELL-P process. The purity of the GVL-IP pulp significantly exceeded that of commercial prehydrolysis kraft (PHK) and prehydrolysis soda-anthraquinone (PH-Soda-AQ) pulps. IONCELL-P extraction removed more than 90% of the hemicelluloses, resulting in a dissolving pulp with a purity of 96% and a high molecular mass fraction, 2.3 times higher than that of a conventional PHK pulp. GVL-IP pulps are suitable not only for regenerated cellulose fibers or films, but also for high-purity, high-viscosity cellulose acetate and ethers, which cannot be produced in an environmentally friendly way by conventional processes.

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