期刊
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO
卷 62, 期 5, 页码 388-401出版社
ELSEVIER
DOI: 10.1016/j.bsecv.2022.06.004
关键词
Nanosilica; Nanoalumina; C-S-H gel; C-A-S-H gel; NMR; Deconvolution
This research investigates the influence of different nanomaterials on the structure of synthetic gels, showing that the incorporation of aluminum in the C-S-H gel can modify its structure. Mixtures with NS OX50 exhibit novel trends.
This research consists of the fabrication of synthetic gels of hydrated calcium silicate (C-S-H gel) and hydrated calcium aluminate silicates (C-A-S-H gel) in aqueous solution oversatu-rated in calcium hydroxide. These gels were fabricated using nanomaterials with different specific surface area; two nanosilicas (NS), OX50 and A200 (50 and 200 m2/g respectively) and two nanoaluminas (NA), A65 and A130 (65 and 130 m2/g). Mixtures were carried out main-taining a Ca/Si = 2 ratio and variable Al/Si ratios of 0.1, 0.5 and 1. The effect of aluminium incorporation in the C-S-H gel was studied using the nuclear magnetic resonance technique (29Si MAS-NMR), and the information obtained was further processed using the mathemat-ical deconvolution method. Chemical shift bands were delimited to identify the structures. From the results obtained, modifications of the tetrahedral (Qn) in the dreierketten struc-ture were observed in the different combinations, as well as the modification of the bridging tetrahedral (Q2b) due to the presence of aluminium replacing the silica bridging tetrahedron Q2b(1Al). High Q4 values were detected in the C-S-H gel with NS OX50 and this could be asso-ciated to a double chain formation very similar to a perfect tobermorite. The length of the mean chains (MCL) was very variable in each blend, but some trends were observed as the Al/Si = 1 ratio and the Al/Si = 0.1 ratio maintain or increases the MCL respectively. The results are interesting and concrete case mixtures with NS OX50 show original trends that have not yet been reported in the literature. (c) 2022 The Authors. Published by Elsevier Espa n similar to a, S.L.U. on behalf of SECV. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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