期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 18, 期 -, 页码 781-787出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.18.78
关键词
azobenzenes; Baeyer-Mills reaction; continuous flow; molecular; switches; solar fuel
资金
- European Regional Development Fund (ERDF)
- Germans Research Council DFG [WE5601/12-1]
- TCI
In this study, a continuous flow setup was used to efficiently synthesize non-symmetric substituted azobenzenes through the Baeyer-Mills coupling reaction. The versatility and scalability of this method were demonstrated.
Azobenzene, as one of the most prominent molecular switches, is featured in many applications ranging from photopharmacology to information or energy storage. In order to easily and reproducibly synthesize non-symmetric substituted azobenzenes in an efficient way, especially on a large scale, the commonly used Baeyer???Mills coupling reaction was adopted to a continuous flow setup. The versatility was demonstrated with a scope of 20 substances and the scalability of this method exemplified by the synthesis of >70 g of an azobenzene derivative applied in molecular solar thermal storage (MOST) systems.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据