Catalytic combustion of CVOCs over MoOx/CeO2 catalysts

MoOx/CeO2 catalysts prepared by impregnation with (NH4)(6)H8Mo7O28 aqueous solution were applied for catalytic oxidation of 1,2-dichloroethane. MoOx exists on CeO2 fluorite as isolated (O=)(2)Mo(O-Ce)(2), poly MoO4 and nano-particles, of which (O=)(2)Mo(O-Ce)(2) presents high acidity and reducibility of Mo, and decreases the basicity of CeO2, leading to the formation of reactive intermediate during 1,2-dichloroethane adsorption. The activity of MoOx/CeO2 catalysts for 1,2-dichloroethane oxidation increases with acidity and surface oxygen from CeO2 domain. The catalyst with 2.6 Mo atom nm(-2) presents the highest apparent activity with T-90 of 280 degrees C in feed containing 1000/2000 ppm 1,2-dichloroethane at 60,000 h(-1) space velocity. For chlorinated aromatic oxidation, similar high stable activity is observed. The ability of (O=)(2)Mo(O-Ce)(2) for water dissociation promotes Cl removal, and thus, the chlorination is inhibited completely within experiment temperature. Mo6+=O of (O=)(2)Mo(O-Ce)(2) is highly stable in wet feed, leading to high resistance of MoOx/CeO2 catalysts to water.

Automated summary

MoOx/CeO2 catalysts with different forms of MoOx on CeO2 were prepared for the catalytic oxidation of 1,2-dichloroethane. The acidity and surface oxygen from CeO2 domain play important roles in the activity of the catalysts.