期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 39, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202208163
关键词
Conductive 2D MOFs; Hydrogen Generation; Photocathode; Photoelectrocatalysis; sp-Carbon
资金
- ERC starting grant (FC2DMOF) [852909]
- EU Graphene Flagship (Core3) [881603]
- ERC Consolidator Grant (T2DCP)
- DFG [417590517]
- EMPIR-20FUN03COMET, H2020-FETOPEN-PROGENY [899205]
- German Science Council
- Center of Advancing Electronics Dresden (cfaed)
- Taishan Scholars Program of Shandong Province [tsqn201909047]
- cluster of excellence UniSysCat [EXC 2008/1-390540038]
- National Science Foundation [CHE-2108197]
- Projekt DEAL
Metal-organic frameworks (MOFs) have high porosity and find broad applications in catalysis and gas separation. However, their insulating feature and limited active sites hinder their use as photocathode active materials in photoelectrocatalytic hydrogen generation. To address this, a layered conductive two-dimensional conjugated MOF (2D c-MOF) with sp-carbon active sites was developed, achieving efficient hydrogen generation.
Metal-organic frameworks (MOFs) have attracted increasing interest for broad applications in catalysis and gas separation due to their high porosity. However, the insulating feature and the limited active sites hindered MOFs as photocathode active materials for application in photoelectrocatalytic hydrogen generation. Herein, we develop a layered conductive two-dimensional conjugated MOF (2D c-MOF) comprising sp-carbon active sites based on arylene-ethynylene macrocycle ligand via CuO4 linking, named as Cu(3)HHAE(2). This sp-carbon 2D c-MOF displays apparent semiconducting behavior and broad light absorption till the near-infrared band (1600 nm). Due to the abundant acetylene units, the Cu(3)HHAE(2) could act as the first case of MOF photocathode for photoelectrochemical (PEC) hydrogen generation and presents a record hydrogen-evolution photocurrent density of approximate to 260 mu A cm(-2) at 0 V vs. reversible hydrogen electrode among the structurally-defined cocatalyst-free organic photocathodes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据