期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 34, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202208326
关键词
Circularly Polarized Luminescence; Lanthanides; Near Infrared (NIR); PyBox
资金
- European Commision Research Executive Agency, Horizon 2020 Research and Innovation Programme under the Marie Sklodowska-Curie grant [859752-HEL4CHIROLED-H2020-MSCA-ITN-2019]
- Italian Ministero dell'Universita [PRIN 20172M3K5N]
- University of Pisa [PRA 2020_21]
- CINECA award under the ISCRA initiative
- University of Pisa within the CRUI-CARE Agreement
Novel chiral Er complexes based on (i)PrPyBox show strong near-infrared circularly polarized luminescence, which has potential applications in fields such as optical communications and bioimaging.
Novel chiral Er complexes based on both enantiomers of extended (i)PrPyBox (2,6-Bis[4-isopropyl-4,5-dihydrooxazol-2-yl)]pyridine) show strong near-infrared circularly polarized luminescence (CPL) within the 1400 to 1600 nm spectral region under 450 nm irradiation. CPL activity in this region, despite being particularly rare, would open the way to potential applications in the domain, e.g., of fiber-optic telecommunications and free-space long-distance optical communications employing circularly polarized light. Moreover, the long wavelength excitation is advantageous for applications in the field of (circularly polarized) microscopy and bioimaging.
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