期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 37, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202206390
关键词
Carbenes; Density Functional Calculations; Molecular Orbitals; N-Heterocyclic Carbene; Radicals
资金
- European Research Council (ERC) under the European Union [948185]
- Fonds der Chemischen Industrie im Verband der Chemischen Industrie
- Projekt DEAL
- European Research Council (ERC) [948185] Funding Source: European Research Council (ERC)
Stabilizing free radicals using C-donor ligands has been investigated by analyzing the pi-donation and pi-acceptance effects. This study provides a new understanding of NHC chemistry and allows for predicting the thermodynamic stability of covalent radicals and quantifying redox non-innocence.
Carbenes, including N-heterocyclic carbene (NHC) ligands, are used extensively to stabilize open-shell transition metal complexes and organic radicals. Yet, it remains unknown, which carbene stabilizes a radical well and, thus, how to design radical-stabilizing C-donor ligands. With the large variety of C-donor ligands experimentally investigated and their electronic properties established, we report herein their radical-stabilizing effect. We show that radical stabilization can be understood by a captodative frontier orbital description involving pi-donation to- and pi-donation from the carbenes. This picture sheds a new perspective on NHC chemistry, where pi-donor effects usually are assumed to be negligible. Further, it allows for the intuitive prediction of the thermodynamic stability of covalent radicals of main group- and transition metal carbene complexes, and the quantification of redox non-innocence.
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