期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 39, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202207927
关键词
Desolvation Energy; Lithium Dendrites; Lithium Metal Batteries; Low Temperature Electrolyte; Solvating Power
资金
- National Natural Science Foundation of China [51771094, 21835004]
- National Key R&D Program of China [2016YFB0901500]
- Ministry of Education of China [B12015]
- Tianjin Natural Science Foundation [18JCZDJC31500]
- Haihe Laboratory of Sustainable Chemical Transformations
This study finds that the solvating power of solvent is closely related to the behavior of lithium deposition at low temperatures in lithium metal batteries. A solvent with weak solvating power enables higher deposition/stripping efficiency and uniform deposition morphology. By designing appropriate electrolyte and electrode materials, stable cycling at low temperatures can be achieved.
For lithium (Li) metal batteries, the decrease in operating temperature brings severe safety issues by more disordered Li deposition. Here, we demonstrate that the solvating power of solvent is closely related to the reversibility of the Li deposition/stripping process under low-temperature conditions. The electrolyte with weakly solvating power solvent shows lower desolvation energy, allowing for a uniform Li deposition morphology, as well as a high deposition/stripping efficiency (97.87 % at -40 degrees C). Based on a weakly solvating electrolyte, we further built a full cell by coupling the Li metal anode with a sulfurized polyacrylonitrile electrode at a low anode-to-cathode capacity ratio for steady cycling at -40 degrees C. Our results clarified the relationship between solvating power of solvent and Li deposition behavior at low temperatures.
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