4.8 Article

Sugar-Derived Isotropic Nanoscale Polycrystalline Graphite Capable of Considerable Plastic Deformation

期刊

ADVANCED MATERIALS
卷 34, 期 31, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202200363

关键词

isotropic materials; nanostructured carbon; plasticity; polycrystalline graphite; van der Waals materials

资金

  1. National Natural Science Foundation of China [52032003, 52102093]

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This article discusses the development of sugar-derived isotropic nanostructured polycrystalline graphite (SINPG), which achieves excellent plasticity by activating the rotation of nanoscale grains, resulting in high compressive strength and plastic strain. This new material is of great significance for various applications in different fields.
Obtaining large plastic deformation in polycrystalline van der Waals (vdW) materials is challenging. Achieving such deformation is especially difficult in graphite because it is highly anisotropic. The development of sugar-derived isotropic nanostructured polycrystalline graphite (SINPG) is discussed herein. The structure of this material preserves the high in-plane rigidity and out-of-plane flexibility of graphene layers and enables prominent plasticity by activating the rotation of nanoscale (5-10 nm) grains. Thus, micrometer-sized SINPG samples demonstrate enhanced compressive strengths of up to 3.0 GPa and plastic strains of 30-50%. These findings suggest a new pathway for enabling plastic deformation in otherwise brittle vdW materials. This new class of nanostructured carbon materials is suitable for use in a broad range of fields, from semiconductor to aerospace applications.

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