4.8 Review

Molecular-Switch-Embedded Solution-Processed Semiconductors

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Future-Oriented Advanced Diarylethene Photoswitches: From Molecular Design to Spontaneous Assembly Systems

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Summary: Diarylethene (DAE) photoswitch, as a smart trigger, has shown superior performance in stimulus-responsive materials. The introduction of DAE into an assembly system has been an attractive strategy, enabling the manifestation of photochromic behavior at the system level, promoting the design and manufacture of advanced materials.

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Molecular Approach to Engineer Two-Dimensional Devices for CMOS and beyond-CMOS Applications

Yuda Zhao et al.

Summary: This paper provides a review of the recent research progress in the functionalization of two-dimensional materials (2DMs). By covalently or noncovalently functionalizing 2DMs with molecules, more efficient charge injection and transport can be achieved, along with stimuli-responsive functionality. The authors introduce the relevant properties of 2DMs, molecules, and molecular switches, and discuss the physical and chemical strategies for synthesizing 2DM/molecule hybrid systems.

CHEMICAL REVIEWS (2022)

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Diarylethenes in Optically Switchable Organic Light-Emitting Diodes: Direct Investigation of the Reversible Charge Carrier Trapping Process

Giovanni F. Cotella et al.

Summary: The study explores optically switchable organic light-emitting diodes (OSOLEDs) based on commercially available light-emitting polymer F8BT doped with a diarylethene derivative. The photochromic activity of the dopant in the solid state and morphology of different blends are investigated. The devices demonstrate a maximum reversible optical threshold voltage shift of 4 V with best performing devices showing a maximum current density and luminance ON/OFF ratio of approximately 20 and 90, respectively.

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Florica Adriana Jerca et al.

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A Molecular-Switch-Embedded Organic Photodiode for Capturing Images against Strong Backlight

Mingyun Kang et al.

Summary: This study proposes a method to overcome early photocurrent saturation in organic photodiodes (OPDs) by introducing a light-intensity-dependent transition of the operation mode. By doping the photoactive layer with a molecular switch, the proposed OPD exhibits high external quantum efficiency under low-intensity and high-intensity light illuminations, extending the photoresponse linearity to a higher light intensity.

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The Tri(imidazole)-Derivative Moiety: A New Category of Electron Acceptors for the Design of Crystalline Hybrid Photochromic Materials

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Simultaneous Incorporation of Two Types of Azo-Groups in the Side Chains of a Conjugated D-A Polymer for Logic Control of the Semiconducting Performance by Light Irradiation

Jianwu Tian et al.

Summary: A new design strategy involving tetra-ortho-methoxy-substituted azobenzene (mAzo) and arylazopyrazole (pAzo) in the side chains is reported for a photoresponsive semiconducting polymer with tri-stable semiconducting states. The trans-cis isomerization of mAzo and pAzo groups can modulate thin film crystallinity, leading to tri-stable semiconducting states in field-effect transistors (FETs) after sequential light irradiation. By utilizing light irradiation at three different wavelengths, the device performance can be logically controlled, and a three-value logic gate can be successfully mimicked using a single FET device.

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Gloria Hong et al.

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End-Functionalization of Diarylethene for Opto-Electronic Switching with High Fatigue Resistance

Syed Zahid Hassan et al.

Summary: This study proposes a molecular and synthetic approach to enhance the switching performance of diarylethene-based organic transistors. By adjusting the length of alkyl side chains, the molecular environment and compatibility with semiconductor matrix can be optimized, resulting in improved light-controlled on/off ratios.

CHEMISTRY OF MATERIALS (2021)

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Halide Perovskite Semiconductor Lasers: Materials, Cavity Design, and Low Threshold

Qing Zhang et al.

Summary: Perovskite lasers, combining the advantages of inorganic and organic semiconductors, have emerged as excellent candidates for solution-processable lasers. They offer cost-effectiveness, low threshold, high coherence, and multicolor tunability. Despite rapid development and various types of lasers and devices, critical issues such as mass fabrication and applications still need to be addressed.

NANO LETTERS (2021)

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Site-Selective Occupancy of Eu2+ toward High Luminescence Switching Contrast in BaMgSiO4-Based Photochromic Materials

Yan Zhu et al.

Summary: By conducting site-selective occupancy engineering on BaMgSiO4:Eu2+ photochromic materials, the luminescence switching contrast was significantly improved, and an effective energy transfer process was established, providing new insights for designing high-performance optical storage systems.

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Multiresponsive Nonvolatile Memories Based on Optically Switchable Ferroelectric Organic Field-Effect Transistors

Marco Carroli et al.

Summary: Organic transistors are crucial for flexible and wearable logic applications, and the pursuit of multiresponsivity is important for enabling sophisticated operations and functions in organic electronics. The first multiresponsive organic device based on a photochromic-ferroelectric organic field-effect transistor has been reported, capable of operating as nonvolatile memory with 11 bit storage capacity in a single device. This proof of concept paves the way for enhanced functional complexity in optoelectronics through the integration of multiple components in a single device.

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Self-Assembled Nanodielectrics for Solution-Processed Top-Gate Amorphous IGZO Thin-Film Transistors

Katie Stallings et al.

Summary: Metal oxide semiconductors, such as a-IGZO, have shown impressive progress as alternatives to amorphous silicon in electronics applications, but require compatible unconventional gate dielectric materials. Solution-processable self-assembled nanodielectrics (SANDs) composed of alternating organic and inorganic oxide layers offer high capacitances and low processing temperatures, yet have not been implemented in the top-gate TFT architecture.

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Wide Bandgap Oxide Semiconductors: from Materials Physics to Optoelectronic Devices

Jueli Shi et al.

Summary: Wide bandgap oxide semiconductors are a unique class of materials with properties of electrical conductivity and optical transparency, widely used in optoelectronics. Recent research focuses on understanding the materials physics and designing new high-performing TFT devices based on oxide semiconductors.

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Engineering Copper Iodide (CuI) for Multifunctional p-Type Transparent Semiconductors and Conductors

Ao Liu et al.

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Light-Programmable Logic-in-Memory in 2D Semiconductors Enabled by Supramolecular Functionalization: Photoresponsive Collective Effect of Aligned Molecular Dipoles

Ye Wang et al.

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Asymmetric Dressing of WSe2 with (Macro)molecular Switches: Fabrication of Quaternary-Responsive Transistors

Haixin Qiu et al.

Summary: The integration of photochromic materials and ferroelectric copolymer layer into WSe2 FET enables remote and reversible control of output current via light, heat, and electric field. The synergistic effects of the photochromic materials and ferroelectric copolymer allow for efficient tuning of carrier concentration and device polarity, promoting the development of advanced 2D electronics.

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Haixin Qiu et al.

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Seong Hoon Yu et al.

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Critical Factors of Diarylethene for a High-Performance Photoprogrammable Polymer Transistor: Crystallographic Compatibility, Quantum Yield, and Fatigue Resistance

Syed Zahid Hassan et al.

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A Wavelength-Tunable Multi-Functional Transistor with Visible-Light Detection and Inverse Photomemory for Logic Gate and Retina Emulation

Qianqian Shi et al.

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Xiuze Hei et al.

Summary: Conventional inorganic semiconductors are renowned for their superior physical properties and chemical robustness, but are limited in other applications due to poor solubility and solution-processability. A new group of hybrid semiconductors based on anionic copper(I) halide and cationic organic ligands has been developed to address these issues, showing improved framework stability and solution processibility.

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