期刊
ADVANCED FUNCTIONAL MATERIALS
卷 32, 期 36, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202204778
关键词
all-solid-state lithium metal batteries; heterogeneous nanodomain electrolytes; long lifespans; phase separation; transport channels
类别
资金
- Outstanding Youth Project of Guangdong Natural Science Foundation [2021B1515020051]
- Science and Technology Program of Guangzhou [2019050001]
- China Postdoctoral Science Foundation [2021M691091]
- Guangdong Basic & Applied Basic Research Foundation [2022A1515011979, 2021A1515110156, 2021A1515110196]
- cultivation foundation of South China Normal University for young teachers [20KJ09]
- Natural Sciences and Engineering Research Council of Canada
- Waterloo Institute for Nanotechnology
- University of Waterloo
This paper introduces a method using Pebax strategy to construct heterogeneous nanodomain electrolytes, which improves the insufficient mechanical strength and ionic conductivity of solid polymer electrolytes in all-solid-state lithium-metal batteries. Compared with conventional electrolytes, Pebax HNEs exhibit better lithium ion transport and deposition performance, as well as the ability to suppress dendrite growth.
Solid polymer electrolytes exhibit huge advantages but are hindered by insufficient mechanical strength and ionic conductivity in the applications of all-solid-state lithium-metal batteries (ASSLBs). Herein, poly(ether-block-amide) (Pebax) strategies to construct heterogeneous nanodomain electrolytes (HNEs) for ultra-long-life ASSLBs are introduced. Pebax HNEs forms conductive nanodomains via phase separation, exhibiting interconnected and high Li+ conductive features. Compared with conventional PEO-based electrolytes, the Pebax HNEs with controllable size and order can facilitate rapid Li+ transport with steerable transport channels, further enhancing the Li+ conductivity and inducing the uniform Li+ deposition. Furthermore, the obtained thin and dense hybrid SEI layer with potent mechanical strength can synergistically suppress the dendrite growth, and the as-prepared ASSLBs exhibit a satisfactory capacity with a tiny capacity reduction of 0.013% per cycle over 1500 cycles. This work provides a brand-new insight to construct a conductive structure in electrolytes for high-performance ASSLBs.
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