期刊
ADVANCED FUNCTIONAL MATERIALS
卷 32, 期 35, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202205115
关键词
asymmetric small molecules; fused-ring electron acceptors; nonfullerene acceptors; organic photovoltaics; organic solar cells
类别
资金
- Scientific Research Foundation of Education Department of Jilin Province [JJKH20220827KJ]
- Natural Science Foundation of Jiangxi Province in China [20212BAB204055]
- Natural Science Foundation of Changchun Normal University
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB36000000]
- National Natural Science Foundation of China [21875052]
- Scientific Startup Fund of Changchun Normal University
This paper reviews the recent progress of Y6-derived asymmetric conjugated molecules, with a focus on the relationship between molecular structure, optoelectronic properties, and device performance. It provides a reference for the future design direction and challenges of this type of photovoltaic materials.
Symmetric conjugated molecules can be broken through suitable synthetic strategies to construct novel asymmetric molecules, which can largely broaden the material library. In the field of organic solar cells, fused-ring electron acceptors (FREAs) with the A-DA'D-A type backbone structure have attracted much attention and enabled power conversion efficiencies (PCE) exceeding 18%. Among them, Y6 is one of the most classic FREAs that can derive many symmetric and asymmetric molecules and exhibit unique optoelectronic properties. Thus, in this review, the focus is on the recent progress of Y6-derived asymmetric FREAs containing a dipyrrolobenzothiadiazole segment, which can be classified as the following three categories: asymmetric end group, asymmetric central core and asymmetric side chain. The relationship of the molecular structure, optoelectronic properties, and device performance is discussed in detail. Finally, the future design directions and challenges faced by this kind of photovoltaic materials are given.
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