期刊
JOURNAL OF CHEMICAL THERMODYNAMICS
卷 102, 期 -, 页码 442-450出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2016.07.031
关键词
Rhodium(III) acetylacetonate; Vapor pressure; Sublimation enthalpy; Sublimation entropy; Heat capacity
资金
- Ministry of Education and Science of the Russian Federation [14.604.21.0080, RFMEFI60414X0080]
Complex of rhodium(III) with acetylacetone (Rh(acac)3) was synthesized, purified and identified for thermochemical study. Vapor pressures of the compound were measured by static and transpiration methods in the temperature range from 398 to 521 K. Thermodynamic characteristics of sublimation process Delta H-sub(459.6) and HsubS degrees (459.6) were determined from the experimental data. Heat capacity in the temperature range from 188 to 465 K was measured by using DSC for the first time. Using experimental results, Delta H-sub(298.15) and Delta subS degrees(298.15) of the compound were derived. (C) 2016 Elsevier Ltd.
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