期刊
JOURNAL OF CHEMICAL THERMODYNAMICS
卷 101, 期 -, 页码 12-18出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2016.05.004
关键词
Urea derivatives; Sulfur dioxide; Solubility; Thermodynamic properties
The solubilities of SO2 in three dipolar aprotic urea diversities, 1,1,3,3-tetramethylurea (TMU), 1,3-dimethyl-2-imidazolidinone (DMI), and 1,3-dimethyl-3,4,5,6-tetrahydro-2 (1H)-pyrimidinone (DMPU) was measured at temperatures ranging from (293.15 to 323.15) K and pressure up to 120 kPa. By correlating the solubility results with a reaction equilibrium thermodynamic model (RETM), Henry's constants (H-m), reaction equilibrium constants (K degrees), and enthalpy (Delta H-r) in the absorption process were obtained. The results indicate that the three solvents exhibit both strong physical and weak chemical interactions with SO2. Further comparison of the capture performance with ILs, deep eutectic solvents (DESs), and several organic solvents, DMI, DMPU and TMU are noted to be excellent absorbents for acidic SO2. (C) 2016 Elsevier Ltd.
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