期刊
JOURNAL OF POLYMER SCIENCE
卷 60, 期 14, 页码 2015-2042出版社
WILEY
DOI: 10.1002/pol.20220122
关键词
nanostructures; porous carbons; pyrolysis; self-assembly; template
资金
- National Science Foundation Office of Integrative Activities [1757220]
- NSF-NRT Interface program [DGE-1449999]
- Office Of The Director
- Office of Integrative Activities [1757220] Funding Source: National Science Foundation
This review focuses on the progress and opportunities of self-assembled polymers in the synthesis of mesoporous carbons (MCs), discussing the established methods for converting nanostructured polymers to MCs and the engineering methods for controlling the pore size and morphology of MCs. The review also includes strategies for functionalizing these materials and a brief perspective on emerging research opportunities in this field.
Polymer self-assembly provides a robust and cost-efficient nanomanufacturing platform for enabling a broad range of applications, such as microelectronics, drug delivery, and separation membranes. This review focuses on discussing the progress and opportunities of self-assembled polymer in the synthesis of mesoporous carbons (MCs), which have aroused significant research interests over the past decades. Specifically, we will discuss the two most established approaches for converting nanostructured polymers to MCs, including templating-based and direct pyrolysis-based methods. We will also review the fundamental ordering mechanisms and kinetics of these polymeric systems and discuss the recent development of engineering methods for providing on-demand control over the pore size and morphology of MCs. Additionally, this review article also includes a section focusing on the strategies to further functionalize these materials from self-assembled polymers to enhance their performance, such as chemical activation, heteroatom doping, introduction of nanoparticles into the carbon matrix, and enhancing graphitization degree of carbon walls. Finally, a brief perspective is provided about the emerging research opportunity in this exciting field.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据