期刊
MEMBRANES
卷 12, 期 3, 页码 -出版社
MDPI
DOI: 10.3390/membranes12030264
关键词
poly(ionic liquids); norbornene; ROMP; block copolymers; membranes; gas separations
类别
资金
- NSF [CHE-1919906]
- Alabama Advanced Solvent Cluster (AASC) - U.S. Department of Energy Established Program to Stimulate Competitive Research (DOE-EPSCoR) [DE-SC0020282]
This study investigates the incorporation of ionic liquids (ILs) into poly(norbornene) to create unique materials with synergistic properties. By synthesizing different types of norbornene-based imidazolium-based ILs and using polymerization reactions, high molecular weight block copolymers were obtained. The resulting membranes displayed good gas separation performance.
Poly(norbornene)s and poly(ionic liquid)s are two different classes of attractive materials, which are known for their structural tunability and thermal stabilities, and have been extensively studied as gas separation membranes. The incorporation of ionic liquids (ILs) into the poly(norbornene) through post-polymerization has resulted in unique materials with synergistic properties. However, direct polymerization of norbornene-containing IL monomers as gas separation membranes are limited. To this end, a series of norbornene-containing imidazolium-based mono- and di-cationic ILs (NBM-mIm and NBM-DILs) with different connectivity and spacer lengths were synthesized and characterized spectroscopically. Subsequently, the poly(NBM-mIm) with bistriflimide [Tf2N-] and poly([NBM-DILs][Tf2N](2)) comprising homo-, random-, and block- (co)polymers were synthesized via ring-opening metathesis polymerization using the air-stable Grubbs second-generation catalyst. Block copolymers (BCPs), specifically, [NBM-mIM][Tf2N] and [NBM-ImC(n)mIm] [Tf2N](2) (n = 4 and 6) were synthesized at two different compositions, which generated high molecular weight polymers with decent solubility relative to homo- and random (co)polymers of [NBM-DILs] [Tf2N](2). The prepared BCPs were efficiently analyzed by a host of analytical tools, including H-1-NMR, GPC, and WAXD. The successfully BCPs were cast into thin membranes ranging from 47 to 125 mu m and their gas (CO2, N-2, CH4, and H-2) permeations were measured at 20 degrees C using a time-lag apparatus. These membranes displayed modest CO2 permeability in a non-linear fashion with respect to composition and a reverse trend in CO2/N-2 permselectivity was observed, as a usual trade-off behavior between permeability and permselectivity.
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