4.7 Article

The Effect of Substrate Treatment on the Properties of TiAlSiYN/CrN Nanocomposite Coatings

期刊

SURFACES AND INTERFACES
卷 30, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.surfin.2022.101902

关键词

Grains and interfaces; Stress/strain measurements; X-ray analysis; Nanocomposite; Wear

资金

  1. Ministry of Education and Science of Ukraine within the state budget program Multilayer and multicomponent coatings with adaptive behavior in wear and friction conditions [0118U003579]
  2. Ministry of Education and Science of Ukraine within the state budget program Implantation of high-energy and low-energy ions into multilayer and multicomponent coatings: microstructure and properties [0119U100787]
  3. Polish Ministry of Science and Higher Education from Science Fund of the Lublin University of Technology, at the Faculty of Electrical Engineering and Computer Science [FN-28/E/EE/2020]
  4. Ministry of Education and Science (Poland) [FD-20/EE-2/709]
  5. project Lublin University of Technology-Regional Excellence Initiative - Polish Ministry of Science and Higher Education [030/RID/2018/19]

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This study examines the mechanical and tribological properties of TiA-SiYN/CrN system for cutting machinery. The experimental data suggests that samples prepared with Cr plasma treatment without Cr interlayer exhibit improved wear, crack resistance, and adhesion to the substrate.
Nanocomposite multilayer coatings are of large interest to the engineering industry because of their functional properties. Titanium nitride-based multilayer structures are very effective as protective layers for mechanical instrumentation. In this paper, selected mechanical and tribological properties for cutting machinery of TiA-SiYN/CrN system were considered. The columnar (111) coherent growth of the TiAlSiYN on the CrN without layers mixing has been identified via TEM and XRD. But crystal orientation, crystallite size and residual strain were varied depending on Cr interlayer and pre-treatment. Analysis of the experimental data manifests a decomposed Ti0.25Al0.75N phase stabilized by CrN that was suggested as one of the main factors responsible for superhard phase formation. Wear and scratch experiments highlighted improved wear, crack resistance and adhesion to the substrate (Lc5 = 150.1 N) in the sample prepared in Cr plasma without Cr interlayer. Cutting analysis proved the exceptional durability of inserts after coating deposition. Fracture mechanisms were found out to carry an adhesive character over the cohesive.

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