Polypyrrole and polyaniline-based membranes for fuel cell devices: A review

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Self-templating synthesis of heteroatom-doped large-scalable carbon anodes for high-performance lithium-ion batteries

Ghulam Yasin et al.

Summary: A new advanced anode material, nitrogen-rich sulfur-doped porous carbon (NSPC), has been developed for lithium-ion batteries, exhibiting high performance and prolonged cycle life.

INORGANIC CHEMISTRY FRONTIERS (2022)

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Article Chemistry, Physical

Iron-cation-coordinated cobalt-bridged-selenides nanorods for highly efficient photo/electrochemical water splitting

Shumaila Ibraheem et al.

Summary: This study reports the fabrication of multi-cation incorporated Fe2+/3+/Co2+ species into selenide nanorods, which enhances the electrocatalytic activity of water splitting by modulating the electronic structure and electron-transfer route. This approach can improve the efficacy of water electrolysis.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Chemistry, Multidisciplinary

Defects-engineered tailoring of tri-doped interlinked metal-free bifunctional catalyst with lower gibbs free energy of OER/HER intermediates for overall water splitting

G. Yasin et al.

Summary: A facile tempted-defects assisted fractionation strategy was presented to synthesize N, S, and O tri-doped metal-free catalyst (DETDAP), which exhibits excellent bifunctional catalytic activity with low overpotential towards both the OER and HER. The tailored defects in tri-doped interlinking were found to enhance the bifunctional catalytic performance, providing a perceptive understanding of the synergetic principles of heteroatom-interlinking-tailoring nanostructures in water splitting.

MATERIALS TODAY CHEMISTRY (2022)

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Review Chemistry, Inorganic & Nuclear

Molecular-MN4 vs atomically dispersed M-N4-C electrocatalysts for oxygen reduction reaction

Anuj Kumar et al.

Summary: This article highlights the motivation for developing efficient O-2 electrocatalysts and the application of molecular electrocatalysts, pointing out the challenges in activity and durability of M-N-4-C materials, and introduces ways to optimize their performance through chemical treatment.

COORDINATION CHEMISTRY REVIEWS (2021)

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Review Energy & Fuels

M-N-C-based single-atom catalysts for H2, O2 & CO2 electrocatalysis: activity descriptors, active sites identification, challenges and prospects

Anuj Kumar et al.

Summary: This review highlights the application of single-atom catalysts in electrocatalytic activation of small molecules, focusing on activity descriptors, recent advancements, characterization techniques, design methods, challenges, and future prospects for metal-nitrogen-carbon based SACs.

FUEL (2021)

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Article Materials Science, Multidisciplinary

Enhancing oxygen reduction reaction performance via CNTs/graphene supported iron protoporphyrin IX: A hybrid nanoarchitecture electrocatalyst

Anuj Kumar et al.

Summary: This study successfully suppressed the aggregation of rGO by forming H@CNTs/rGO composite, which increased the number of active sites for ORR. This opens up new opportunities for enhancing various catalytic performances of metal complexes using nanocarbons.

DIAMOND AND RELATED MATERIALS (2021)

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Article Engineering, Environmental

Highly active sites of Pt/Er dispersed N-doped hierarchical porous carbon for trifunctional electrocatalyst

Muhammad Nadeem et al.

Summary: A facile strategy was adopted to uniformly disperse Pt/Er active sites on a carbon structure, achieving efficacious trifunctional catalytic activity for hydrogen/oxygen evolution and oxygen reduction reaction in the developed Pt-Er@PCN-900 product. Pt-Er@PCN-900 with 8% Pt exhibited better performance than commercial 20%Pt/C, highlighting the importance of rationalized dispersion of Pt/Er active sites for future large-scale commercial applications of fuel cell and water splitting.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

A novel CoN4-driven self-assembled molecular engineering for oxygen reduction reaction

Anuj Kumar et al.

Summary: A nanocomposite (g-[Co2N8]) with excellent ORR performance was synthesized by coordinating CoN4 macrocyclic moieties on the graphene surface, outperforming 20% Pt/C catalyst and showing good stability. This work provides insights for designing multi-metallic coordination polymers for energy-related electrocatalysis involving different metal ions in N-4-arrangement.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Physical

Defective/graphitic synergy in a heteroatom-interlinked-triggered metal-free electrocatalyst for high-performance rechargeable zinc-air batteries

Ghulam Yasin et al.

Summary: This study explores the synergistic reaction principles of heteroatom-interlinked-triggering nanomaterials in zinc-air batteries, achieving superior half-wave potential and lowest overpotential for oxygen reduction and oxygen evolution reactions, leading to enhanced catalytic efficiency.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Photoelectrochemical reduction of N2 to NH3 under ambient conditions through hierarchical MoSe2@g-C3N4 heterojunctions

Muhammad Asim Mushtaq et al.

Summary: The hybrid MoSe2@g-C3N4 micro/nanostructures described in this study serve as efficient photoelectrochemical catalysts for fixing N-2 into NH3. The high activity is attributed to the hierarchical architecture, light-harvesting capability, tunable active sites, and formation of heterojunctions at the interface.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Inorganic & Nuclear

The chemistry, recent advancements and activity descriptors for macrocycles based electrocatalysts in oxygen reduction reaction

Anuj Kumar et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Physical

Mechanistic performance of polyaniline-substituted hexagonal boron nitride composite as a highly efficient adsorbent for the removal of phosphate, nitrate, and hexavalent chromium ions from an aqueous environment

Perumal Karthikeyan et al.

APPLIED SURFACE SCIENCE (2020)

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Article Chemistry, Multidisciplinary

High-Voltage and Ultrastable Aqueous Zinc-Iodine Battery Enabled by N-Doped Carbon Materials: Revealing the Contributions of Nitrogen Configurations

Donglin Yu et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Article Chemistry, Inorganic & Nuclear

Boosting oxygen reduction reaction activity by incorporating the iron phthalocyanine nanoparticles on carbon nanotubes network

Anuj Kumar et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2020)

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Review Polymer Science

Recent Progress in Conducting Polymers for Hydrogen Storage and Fuel Cell Applications

Neelima Mahato et al.

POLYMERS (2020)

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Article Chemistry, Inorganic & Nuclear

A novel strategy for the synthesis of hard carbon spheres encapsulated with graphene networks as a low-cost and large-scalable anode material for fast sodium storage with an ultralong cycle life

Ghulam Yasin et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Electrochemistry

Modeling Water Electrolysis in Bipolar Membranes

Jacob A. Wrubel et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

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Review Chemistry, Physical

Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries

Ghulam Yasin et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Promoting electrochemical conversion of CO2 to formate with rich oxygen vacancies in nanoporous tin oxides

Tengfei Gao et al.

CHINESE CHEMICAL LETTERS (2019)

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Article Thermodynamics

High-performance and durable cathode catalyst layer with hydrophobic C@PTFE particles for low-Pt loading membrane assembly electrode of PEMFC

Meng Wang et al.

ENERGY CONVERSION AND MANAGEMENT (2019)

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Article Materials Science, Multidisciplinary

Facile and large-scalable synthesis of low cost hard carbon anode for sodium-ion batteries

Ghulam Yasin et al.

RESULTS IN PHYSICS (2019)

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Article Engineering, Environmental

Decreased charge transport distance by titanium mesh-membrane assembly for flow-electrode capacitive deionization with high desalination performance

Fan Yang et al.

WATER RESEARCH (2019)

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Article Thermodynamics

Fuel cell membranes - Pros and cons

Emmanuel Ogungbemi et al.

ENERGY (2019)

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Article Chemistry, Physical

Improving cell performance and alleviating performance degradation by constructing a novel structure of membrane electrode assembly (MEA) of DMFCs

Wei Sun et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

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Review Chemistry, Physical

Recent Advances for MOF-Derived Carbon-Supported Single-Atom Catalysts

Aijuan Han et al.

SMALL METHODS (2019)

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Article Chemistry, Physical

Rapid and efficient uranium(VI) capture by phytic acid/polyanilinei/FeOOH composites

Xintao Wei et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

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Article Electrochemistry

The Effect of Membrane Properties on Performance and Transports inside Polymer Electrolyte Membrane Fuel Cells

S. Shimpalee et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

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Article Thermodynamics

Self-humidifying Pt-C/Pt-TiO2 dual-catalyst electrode membrane assembly for proton-exchange membrane fuel cells

H. N. Yang et al.

ENERGY (2017)

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Article Chemistry, Physical

Unraveling micro- and nanoscale degradation processes during operation of high-temperature polymer-electrolyte-membrane fuel cells

K. Hengge et al.

JOURNAL OF POWER SOURCES (2017)

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Article Chemistry, Multidisciplinary

Fabrication and performance evaluation of a novel membrane electrode assembly for DMFCs

Meissam Noroozifar et al.

RSC ADVANCES (2016)

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Article Thermodynamics

Optimization of a porous carbon nanofiber layer for the membrane electrode assembly in DMFC

A. M. Zainoodin et al.

ENERGY CONVERSION AND MANAGEMENT (2015)

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Article Chemistry, Physical

Evaluation of polyaniline-Nafion® composite membranes for direct methanol fuel cells durability tests

R. Escuciero-Cid et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2015)

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Review Polymer Science

Utilization of Conducting Polymers in Fabricating Polymer Electrolyte Membranes for Application in Direct Methanol Fuel Cells

Kingshuk Dutta et al.

POLYMER REVIEWS (2014)

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Article Engineering, Chemical

New cross-linked PVA based polymer electrolyte membranes for alkaline fuel cells

Geraldine Merle et al.

JOURNAL OF MEMBRANE SCIENCE (2012)

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Review Energy & Fuels

A review on methanol crossover in direct methanol fuel cells: challenges and achievements

Mahmoud Ahmed et al.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2011)

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Article Engineering, Chemical

Correlation of structural differences between Nafion/polyaniline and Nafion/polypyrrole composite membranes and observed transport properties

Birgit Schwenzer et al.

JOURNAL OF MEMBRANE SCIENCE (2011)

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Article Chemistry, Physical

Surface modification of heteropoly acid/SPEEK membranes by polypyrrole with a sandwich structure for direct methanol fuel cells

Dan Xu et al.

JOURNAL OF MATERIALS CHEMISTRY (2010)

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Article Engineering, Chemical

A new self-cross-linked, net-structured, proton conducting polymer membrane for high temperature proton exchange membrane fuel cells

Sambhu Bhadra et al.

JOURNAL OF MEMBRANE SCIENCE (2010)

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Article Chemistry, Physical

Sulfonated poly(fluorenyl ether ketone nitrile) electrolyte membrane with high proton conductivity and low water uptake

S. H. Tian et al.

JOURNAL OF POWER SOURCES (2010)

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Article Electrochemistry

A Dusty Fluid Model for Predicting Hydroxyl Anion Conductivity in Alkaline Anion Exchange Membranes

Kyle N. Grew et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2010)

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Article Engineering, Chemical

Preparation and characterization of sulfonated poly(arylene ether ketone ketone sulfone)s for ion exchange membranes

Zhe Wang et al.

DESALINATION (2009)

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Article Chemistry, Physical

Layer-by-layer self-assembly of in situ polymerized polypyrrole on sulfonated poly(arylene ether ketone) membrane with extremely low methanol crossover

Haidan Lin et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2009)

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Article Chemistry, Physical

A composite anode with reactive methanol filter for direct methanol fuel cell

Chieh-Hao Wan et al.

JOURNAL OF POWER SOURCES (2009)

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Article Chemistry, Physical

Nafion/polyaniline composite membranes specifically designed to allow proton exchange membrane fuel cells operation at low humidity

Jinyan Yang et al.

JOURNAL OF POWER SOURCES (2009)

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Article Chemistry, Physical

Reaction analysis of a direct methanol fuel cell employing a porous carbon plate operated at high methanol concentrations

Nobuyoshi Nakagawa et al.

JOURNAL OF POWER SOURCES (2009)

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Article Chemistry, Physical

Low methanol-permeable polyaniline/Nafion composite membrane for direct methanol fuel cells

C. -H. Wang et al.

JOURNAL OF POWER SOURCES (2009)

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Article Electrochemistry

Properties of proton-conducting Nafion-type membranes with Nanometer-thick polyaniline surface layers

I. Yu. Sapurina et al.

RUSSIAN JOURNAL OF ELECTROCHEMISTRY (2009)

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Article Engineering, Chemical

Sulfonated montmorillonite/sulfonated poly(ether ether ketone) (SMMT/SPEEK) nanocomposite membrane for direct methanol fuel cells (DMFCs)

Rapee Gosalawit et al.

JOURNAL OF MEMBRANE SCIENCE (2008)

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Article Engineering, Chemical

Influence of oxidation state of polyaniline on physicochemical and transport properties of Nafion/polyaniline composite membrane for DMFC

Bong Gill Choi et al.

JOURNAL OF MEMBRANE SCIENCE (2008)

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Article Engineering, Chemical

Proton conductivity of acid-doped meta-polyaniline

Zhiwei Yang et al.

JOURNAL OF MEMBRANE SCIENCE (2008)

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Article Chemistry, Physical

Chemical modification of Nafion membrane with 3,4-ethylenedioxythiophene for direct methanol fuel cell application

Lei Li et al.

JOURNAL OF POWER SOURCES (2008)

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Article Chemistry, Physical

Surface chemistry and physical properties of Nafion/polypyrrole/Pt composite membrane prepared by chemical in situ polymerization for DMFC

HoSeok Park et al.

JOURNAL OF POWER SOURCES (2008)

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Article Chemistry, Physical

Methanol permeability and proton conductivity of Nafion membranes modified electrochemically with polyaniline

Q. M. Huang et al.

JOURNAL OF POWER SOURCES (2008)

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Article Chemistry, Physical

Formation and evaluation of semi-IPN of nafion 117 membrane for direct methanol fuel cell - 1. Crosslinked sulfonated polystyrene in the pores of nafion 117

P. P. Kundu et al.

JOURNAL OF POWER SOURCES (2007)

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Article Engineering, Environmental

Preparation and characterization of Pt direct deposition on polypyrrole modified nafion composite membranes for direct methanol fuel cell applications

Lei Li et al.

CHEMICAL ENGINEERING JOURNAL (2007)

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Review Chemistry, Physical

A review of polymer electrolyte membranes for direct methanol fuel cells

Vladimir Neburchilov et al.

JOURNAL OF POWER SOURCES (2007)

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Article Chemistry, Physical

Water and air management systems for a passive direct methanol fuel cell

Gregory Jewett et al.

JOURNAL OF POWER SOURCES (2007)

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Direct methanol fuel cell with extended reaction zone anode: PtRu and PtRuMo supported on graphite felt

Alex Bauer et al.

JOURNAL OF POWER SOURCES (2007)

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Article Chemistry, Physical

Effect of current-collector structure on performance of passive micro direct methanol fuel cell

W. M. Yang et al.

JOURNAL OF POWER SOURCES (2007)

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Real time measurements of methanol crossover in a DMFC

Jiahua Han et al.

JOURNAL OF POWER SOURCES (2007)

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Systematic analysis of the direct methanol fuel cell

T. Schultz et al.

JOURNAL OF APPLIED ELECTROCHEMISTRY (2007)

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Article Electrochemistry

Proton exchange membranes based on modified sulfonated poly(ether ether ketone) membranes with chemically in situ polymerized polypyrrole

Song Xue et al.

ELECTROCHIMICA ACTA (2006)

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Article Chemistry, Physical

Preparation and properties of sulfonated poly(ether ether ketone)s (SPEEK)/polypyrrole composite membranes for direct methanol fuel cells

Xianfeng Li et al.

JOURNAL OF POWER SOURCES (2006)

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Article Electrochemistry

Formation and characterization of PEDOT-modified Nafion 117 membranes

L. Li et al.

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2006)

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Article Engineering, Chemical

Nafion®/clay-SO3H membrane for proton exchange membrane fuel cell application

Philippe Bebin et al.

JOURNAL OF MEMBRANE SCIENCE (2006)

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Article Electrochemistry

Optimisation of polypyrrole/Nafion composite membranes for direct methanol fuel cells

Jun Zhu et al.

ELECTROCHIMICA ACTA (2006)

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Physical and electrochemical properties of Nafion/polypyrrole composite membrane for DMFC

HS Park et al.

JOURNAL OF MEMBRANE SCIENCE (2006)

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Article Chemistry, Physical

Characterization and transport properties of Nafion/polyaniline composite membranes

S Tan et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2005)

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Article Electrochemistry

Preparation of a novel composite material based on a Nafion® membrane and polypyrrole for potential application in a PEM fuel cell

S Moravcová et al.

JOURNAL OF APPLIED ELECTROCHEMISTRY (2005)

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Article Chemistry, Multidisciplinary

Pd-Ti and Pd-Co-Au electrocatalysts as a replacement for platinum for oxygen reduction in proton exchange membrane fuel cells

JL Fernández et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

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Article Chemistry, Multidisciplinary

Single-wall carbon nanotube-based proton exchange membrane assembly for hydrogen fuel cells

G Girishkumar et al.

LANGMUIR (2005)

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Article Electrochemistry

Chemical modification of perfluorosulfonated membranes with pyrrole for fuel cell application:: Preparation, characterisation and methanol transport

F Xu et al.

FUEL CELLS (2005)

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Article Chemistry, Physical

Mixed conductive blends of SPEEK/PANI

J Roeder et al.

SOLID STATE IONICS (2005)

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Article Polymer Science

Influence of morphology on the transport properties of perfluorosulfonate ionomers/polypyrrole composite membrane

HS Park et al.

MACROMOLECULES (2005)

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Article Chemistry, Physical

Nafion-Nafion/polyvinylidene fluoride-Nation laminated polymer membrane for direct methanol fuel cells

HJ Kim et al.

JOURNAL OF POWER SOURCES (2004)

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Article Electrochemistry

Comparison of methanol crossover among four types of Nafion membranes

J Ling et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2004)

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Article Chemistry, Physical

Grafting of styrene on to Nafion membranes using supercritical CO2 impregnation for direct methanol fuel cells

J Sauk et al.

JOURNAL OF POWER SOURCES (2004)

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Article Chemistry, Physical

A modified Nafion membrane with in situ polymerized polypyrrole for the direct methanol fuel cell

MA Smit et al.

JOURNAL OF POWER SOURCES (2003)

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Article Electrochemistry

Characteristics of polypyrrole/Nafion composite membranes in a direct methanol fuel cell

EB Easton et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2003)

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Article Chemistry, Physical

Chemically-modified Nafion®/poly(vinylidene fluoride) blend ionomers for proton exchange membrane fuel cells

MK Song et al.

JOURNAL OF POWER SOURCES (2003)

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Article Electrochemistry

Macro- and microscopic properties of nonaqueous proton conducting membranes based on PAN

D Satolli et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2003)

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Article Engineering, Chemical

Sulfonated poly(ether ether ketone) membranes for direct methanol fuel cell

L Li et al.

JOURNAL OF MEMBRANE SCIENCE (2003)

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Article Chemistry, Physical

Grafting and electrochemical characterisation of poly-(3,4-ethylenedioxythiophene) films, on Nafion and on radiation-grafted polystyrenesulfonate-polyvinylidene fluoride composite surfaces

SJ Higgins et al.

JOURNAL OF MATERIALS CHEMISTRY (2003)

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Article Chemistry, Physical

Methanol crossover in direct methanol fuel cells: a link between power and energy density

B Gurau et al.

JOURNAL OF POWER SOURCES (2002)

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Article Electrochemistry

Nafion® 115/zirconium phosphate composite membranes for operation of PEMFCs above 100 °C

P Costamagna et al.

ELECTROCHIMICA ACTA (2002)

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Article Chemistry, Physical

Radiation-modified Nafion membranes for methanol fuel cells

Z Florjanczyk et al.

SOLID STATE IONICS (2001)

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Polypyrrole and polyaniline-based membranes for fuel cell devices: A review

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