期刊
JOURNAL OF CATALYSIS
卷 344, 期 -, 页码 680-691出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2016.10.016
关键词
Mesoporous Al2O3; Crystal forms; Hydrodesulfurization; Dibenzothiophene; 4,6-Dimethyldibenzothiophene; Reaction network
资金
- National Natural Science Foundation of China [21676298, U1463207, 21276277]
- Opening Project of the Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology [2015K003]
- CNPC Key Research Project
- CNOOC project [CNOOC-KJ 135 FZDXM 00 LH 003 LH-2016]
Mesoporous Al2O3 (MA) materials with different crystal forms were synthesized from the boehmite sol. A series of MA materials were used as supports for sulfided NiMo catalysts in the hydrodesulfurization (HDS) of dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT). The as-synthesized MA materials with different crystal forms and the corresponding NiMo catalysts were characterized using XRD, nitrogen physisorption, FTIR, pyridine FTIR, UV-vis, Raman, H-2 TPR, XPS, and HRTEM characterization methods. The NiMo/delta-Al2O3 (NiMo/delta-MA) catalyst exhibited the highest DBT and 4,6-DMDBT conversion at all the weight hourly space velocities (WHSVs); moreover, its DBT conversion (99.6%) was about twice that of the commercial NiMo/Al2O3 (NiMo/C-MA) catalyst (50.2%), while its 4,6-DMDBT conversion (65.8%) was more than four times that of the NiMo/C-MA catalyst (15.5%) at 613 K, 4.0 MPa, 200 ml/ml, and 150 h(-1). The superior catalytic performance of the NiMo/delta-MA catalyst could be ascribed to the synergistic effect of desirable textural properties, moderate acidity, suitable metal-support interaction, appropriate dispersion, and excellent stacking morphology of the active phases. 4,6-DMDBT HDS over the NiMo/delta-MA catalyst showed the highest HYD/DDS ratio (3.08), indicating that the HYD pathway was the main reaction route. Furthermore, an HDS reaction network was proposed for 4,6-DMDBT over NiMo/delta-MA. (C) 2016 Elsevier Inc. All rights reserved.
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