4.6 Article

Microstructure and hot deformation behavior of the Cu-1Ni-0.9Sn-0.5Ti-0.3Cr alloy

期刊

MATERIALS TODAY COMMUNICATIONS
卷 31, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.mtcomm.2022.103771

关键词

Cu-1Ni-0.9Sn-0.5Ti-0.3Cr alloy; Hot deformation behavior; Constitutive equation; Processing map; Microstructure evolution

资金

  1. National Natural Science Foundation of China [52071134]
  2. Program for Innovative Research Team at the University of Henan Province [22IRTSTHN001]
  3. China Postdoctoral Science Foundation [2020M682316, 2021T140779]
  4. Outstanding Talents Innovation Fund of the Henan Province [ZYQR201912164]
  5. Mega grant from the Government of the Russian Federation [220, 075-15-2021-612]

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In this study, the optimal hot processing conditions of the Cu-1Ni-0.9Sn-0.5Ti-0.3Cr alloy were determined, and the microstructure and texture changes were analyzed, providing references for the production and application of the alloy.
The Cu-1Ni-0.9Sn-0.5Ti-0.3Cr alloy was prepared by vacuum induction melting. The hot deformation experiments with the alloy were carried out using the Gleeble-1500 deformation simulation device at 0.001-10 s -1 strain rate, and 500-900 degrees C deformation temperature. The hot working constitutive equation for the Cu-1Ni0.9Sn-0.5Ti-0.3Cr alloy was established. The optimal hot processing of the Cu-1Ni-0.9Sn-0.5Ti-0.3Cr alloy is at 725-900 degrees C and 0.01-0.223 s(-1) strain rate, so the alloy can obtain the required defect-free structure and excellent machinability. The alloy microstructure was analyzed using the electron backscatter diffraction, and the main texture of the Cu-1Ni-0.9Sn-0.5Ti-0.3Cr alloy deformed at 800 degrees C is the {011}< 100 > Goss texture, which is replaced by the {011}< 211 > brass texture at 900 degrees C. Recrystallization is promoted by higher deformation temperature. The recrystallization process provides energy for recrystallization by consuming dislocations, and the geometrically necessary dislocation density decreases with temperature. Transmission electron microscopy of the alloy shows that the precipitates are mainly Cu and NiTi phases. The interface between the two precipitated phases is semi-coherent. The precipitated phase at a semi-coherent interface can produce smaller elastic stress and lower interfacial energy, thus improving the refinement rate. Meanwhile, the Cu and NiTi phases have high toughness, and grain refinement can effectively improve the strength and hardness of the alloy.

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