Magnetoelectric reduction of chromium(VI) to chromium(III)

Toxic heavy-metal pollution represents one of the most pressing environmental challenges that humankind faces today. The conventional approaches for removing highly toxic and carcinogenic heavy metals are currently unsuitable for practical applications. The reduction of harmful heavy metals, such as hexavalent chromium (Cr(VI)) into less harmful trivalent chromium Cr(III), has been gaining considerable interest. In response to this, UV light based photocatalysts have been comprehensively investigated for the reduction of various problematic heavy metals. However, for practical applications, using light as a solution can be highly inefficient owing to poor light absorption in murky or colored heavy metal contaminated water. Here, we demonstrate that wireless magnetic fields can induce the reduction of toxic heavy metals. Core-shell magnetoelectric CoFe2O4 @BiFeO3 nano-octahedral particles were fabricated and used for the catalytic reduction of Cr(VI) via the magnetoelectric effect. We have conducted trapping experiments to propose a mechanism behind the magnetoelectric-effect catalytic reduction. We have achieved reduction of 86% of toxic Cr(VI) using a scavenger for singlet oxygen. In addition, we show the concomitant reduction of Cr(VI) and degradation of an organic pollutant, methylene blue, in a synergistic manner, where the presence of methylene blue accelerates the reduction of Cr(VI) to Cr(III). (c) 2021 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ )

Automated summary

Toxic heavy-metal pollution poses a significant threat to the environment and human health. Conventional removal methods are not practical, leading to a growing interest in reduction treatments. Researchers have discovered that wireless magnetic fields can induce the reduction of toxic heavy metals, proposing a catalytic reduction mechanism based on the magnetoelectric effect.