☆ 4.5 Review

Environmental monitoring approaches for the detection of organic contaminants in marine environments: A critical review

TRENDS IN ENVIRONMENTAL ANALYTICAL CHEMISTRY (2022)

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Article Environmental Sciences

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Zeyuan Li et al.

Summary: This study monitored polycyclic aromatic hydrocarbons (PAHs) in seawater and sediment at eight sites in Shandong Peninsula, China and assessed their ecological risks and biological effects. The results showed that S2 site had the highest pollution, as indicated by both PAHs concentrations and biomarker responses. The integrated biomarker response was found to be a useful tool for marine environmental monitoring when combined with sediment quality guidelines.

JOURNAL OF ENVIRONMENTAL SCIENCES (2022)

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Article Environmental Sciences

A margin of safety approach for the assessment of environmentally realistic chemical mixtures in the marine environment based on combined passive sampling and ecotoxicity testing

Samuel Moeris et al.

Summary: A method for effect-based monitoring of environmentally realistic chemical mixtures was developed using passive sampling and ecotoxicity testing, with margin of safety calculated based on no observed effect concentrations. Diatom growth inhibition was observed at REF >= 3.2 across eight marine samples, with margins of safety found between REF 1.1-11.0. Reconstitution of extracts in HPLC water overcame solvent-related challenges in biotesting, allowing for REFs up to 44 to be achieved.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Article Environmental Sciences

Aquatic toxicity evaluations of PFOS and PFOA for five standard marine endpoints

Nicholas T. Hayman et al.

Summary: The study evaluated the toxicity of PFOS and PFOA on four marine testing species and found the sensitivity ranking of M. galloprovincialis, S. purpuratus, P. lunula, and A. bahia. The results suggest that these species and endpoints are sensitive to PFAS, making them suitable for deriving toxicity data for other PFAS in marine ecosystems.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Toxicity assessment of total petroleum hydrocarbons in aquatic environments using the bioluminescent bacterium Aliivibrio fischeri

Marzieh Mirjani et al.

Summary: This study presents a rapid, sensitive, and cost-effective method for detecting TPHs using Aliivibrio fischeri bioluminescence inhibition bioassay. The optimal conditions for A. fischeri growth were determined, and both short-term and long-term toxicity assays were conducted. The results showed that the best time for bacterial growth was 16 hours after inoculation, and the optimal temperature and pH were 25 degrees Celsius and 7, respectively. The long-term assay returned results after 6 hours, with an EC50 of 1.77 mg/L for TPHs.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2021)

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Article Environmental Sciences

Chlorinated paraffins (SCCPs and MCCPs) in corals and water-SPM-sediment system in the Persian Gulf, Iran: A potential global threat for coral reefs

Ali Ranjbar Jafarabadi et al.

Summary: The study identified the presence of chlorinated paraffins in coral species at the Larak coral reef. Soft corals were found to accumulate more chlorinated paraffins than Scleractinian corals, with zooxanthellae and mucus accumulating more chlorinated paraffins than tissue and skeleton. Congener group patterns were dominated by C-13 for SCCPs and C-17 for MCCPs, with some alterations between mucus and other coral compartments. High loadings of chlorinated paraffins were detected in the skeletons of bleached corals, and a negative correlation between chlorinated paraffin levels and symbiodinium density was observed.

ENVIRONMENTAL POLLUTION (2021)

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Article Environmental Sciences

Rapid and cost-effective multiresidue analysis of pharmaceuticals, personal care products, and antifouling booster biocides in marine sediments using matrix solid phase dispersion

Karina Lotz Soares et al.

Summary: This study developed a fast and inexpensive method for the multi-residue determination of 59 contaminants of emerging concern in sediment, demonstrating high sensitivity, good linearity, satisfactory accuracy, and precision. The proposed method was found to be more environmentally friendly, cheaper, simpler, and faster compared to traditional techniques.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Screening of pharmaceuticals in coastal waters of the southern coast of Viti Levu in Fiji, South Pacific

Jasha Dehm et al.

Summary: The global reliance on pharmaceuticals and lack of effective treatment methods has led to a pseudo-persistence of pharmaceuticals in the environment. This study in Fiji's southern coastal waters found measurable concentrations of pharmaceutical residues, indicating that these pollutants are not limited to highly populated areas.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Use of comprehensive target analysis for determination of contaminants of emerging concern in a sediment core collected from Beppu Bay, Japan

Kou Nishimuta et al.

Summary: A comprehensive target analysis method was used to identify potential contaminants of emerging concern (CECs) in sediment samples collected from Beppu Bay, Japan. The study detected 80 compounds, including three PAHs and TIPPP isomers, with concentrations increasing with decreasing sediment depth. These findings suggest that these chemicals may be categorized as potential CECs in marine environments.

ENVIRONMENTAL POLLUTION (2021)

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Article Environmental Sciences

Organic pollutants in marine samples from Tunisian coast: Occurrence and associated human health risks

Amel Jebara et al.

Summary: A total of 140 contaminants belonging to various classes were simultaneously analysed in marine samples from five stations along the coast of Tunisia, with only 28 residues detected above relative LOQ values. Sediment samples showed slight variation in contaminant residues among coastal stations, while aquatic plant leaves exhibited the highest residue accumulation. Fish samples from the central coast of Tunisia did not pose direct hazard to human health as values were lower than protection limits.

ENVIRONMENTAL POLLUTION (2021)

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Article Environmental Sciences

Comparative field study on bioassay responses and micropollutant uptake of POCIS, Speedisk and SorbiCell polar passive samplers

M. Thao Nguyen et al.

Summary: This study compared three polar passive sampling (PS) devices - Speedisk, SorbiCell, and POCIS - for effect-based water quality monitoring. Chemical analysis and bioassay responses showed that POCIS outperformed Speedisk in detecting a wider range of polar compounds, making it better suited for semi-quantitative effect-based monitoring strategies.

ENVIRONMENTAL TOXICOLOGY AND PHARMACOLOGY (2021)

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Article Engineering, Environmental

Extended suspect screening to identify contaminants of emerging concern in riverine and coastal ecosystems and assessment of environmental risks

Mira Celic et al.

Summary: A suspect screening methodology was developed to identify 360 contaminants of emerging concern in the Ebro Delta, Spain. Among these suspects, 37 compounds were tentatively identified, with 22 fully confirmed. The compounds included pesticides, pharmaceuticals, personal care products, stimulants, and metabolites, with ten compounds being of high ecological concern as potential markers of anthropogenic contamination.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Analytical

First study of passive sampling to monitor short-chain chlorinated paraffins in water: Comparing capabilities of Chemcatcher® and silicone rubber samplers

Mathilde Godere et al.

Summary: Short-chain chlorinated paraffins (SCCPs) are high-volume chemicals of concern, with limited documentation on their occurrence in water environments. Passive sampling has been increasingly used to monitor such complex mixtures efficiently and two proven passive samplers, silicone rubbers and Chemcatcher (R), have shown good applicability in water bodies.

TALANTA (2021)

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Article Marine & Freshwater Biology

Zebrafish as the toxicant screening model: Transgenic and omics approaches

Keng Po Lai et al.

Summary: The production of synthetic compounds and environmental pollutants pose risks to the ecosystem and health, with endocrine disrupting chemicals regarded as a major global issue. Zebrafish are widely used in aquatic toxicology, and omics approaches are employed to study toxicities of EDCs.

AQUATIC TOXICOLOGY (2021)

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Article Environmental Sciences

Levels and trends of synthetic musks in marine bivalves from French coastal areas

Yann Aminot et al.

Summary: The levels and trends of four bioaccumulative synthetic musks were investigated along the French coasts since 2010, showing their extensive occurrence and geographical variations. The study highlighted high concentrations of polycyclic musks HHCB and AHTN, while nitromusks were found in lower levels. The data analysis provided reference for future studies on the occurrence of personal care products on European coasts.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Miniaturised marine tests as indicators of aromatic hydrocarbon toxicity: Potential applicability to oil spill assessment

Katherine A. Colvin et al.

Summary: Using the target lipid model, a study compared the sensitivity of two commercially available marine toxicity tests to aromatic hydrocarbons. The results indicate that rapid cyst-based assays are not sensitive in detecting hydrocarbon exposures, highlighting their limitations in oil pollution monitoring and decision-making.

MARINE POLLUTION BULLETIN (2021)

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Article Environmental Sciences

Aquatic contaminants in Solomon Islands and Vanuatu: Evidence from passive samplers and Microtox toxicity assessment

A. J. Smith et al.

Summary: Water quality issues are increasing in many Pacific countries, with a lack of resources to assess complex chemical contaminants in countries like Vanuatu and Solomon Islands. The extent and impact of chemical contamination in the marine and coastal environment is poorly described, but new data from the use of passive chemical samplers and rapid ecotoxicology tests suggest concerning levels of agricultural and industrial pollutants. These techniques could be applied across the region to generate critical environmental management data and measure the impact of policy changes.

MARINE POLLUTION BULLETIN (2021)

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Hydrocarbon pollution in Atlantic coast of Mauritania (Levrier Bay Zone): Call for sustainable management*

Cherif Ahmed Ahmed Elmamy et al.

Summary: Levrier Bay is an important fishing area facing growing anthropogenic pressures, with PAHs levels lower than in heavily polluted areas but still of concern. Analysis shows pyrogenic sources dominate, with automotive traffic contributing to some extent. Monitoring systems are urgently needed to protect this valuable resource.

MARINE POLLUTION BULLETIN (2021)

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Multiclass analysis of emerging organic contaminants in tropical marine biota using improved QuEChERS extraction followed by LC MS/MS

Tuan Fauzan Tuan Omar et al.

Summary: This study developed a method combining QuEChERS and solid phase extraction cleanup with detection using liquid chromatography with tandem mass spectrometry for trace quantification of EOCs in biota matrices. Trace concentrations of EOCs ranging from 0.05 to 10.76 ng/g were found in biota matrices collected from the Klang River estuary, with 10 compounds detected.

MICROCHEMICAL JOURNAL (2021)

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Article Environmental Sciences

Terrestrial inputs govern spatial distribution of polychlorinated biphenyls (PCBs) and hexachlorobenzene (HCB) in an Arctic fjord

Sverre Johansen et al.

Summary: This study investigates how secondary sources from land influence the occurrence and fate of POPs in an Arctic coastal marine system. Passive sampling of water, riverine SPM, and marine sediments for analysis of PCBs and HCB was conducted in the Isfjorden system, Svalbard, revealing low contaminant concentrations in riverine SPM.

ENVIRONMENTAL POLLUTION (2021)

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Article Environmental Sciences

Dynamic passive sampling of hydrophobic organic compounds in surface seawater along the South Atlantic Ocean east-to-west transect and across the Black Sea

Jaromir Sobotka et al.

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MARINE POLLUTION BULLETIN (2021)

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A Simple Teabag Equilibrium Passive Sampler using hydrophilic divinylbenzene sorbent for contaminants of emerging concern in the marine environment

Francis Vanryckeghem et al.

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