期刊
FRONTIERS IN MATERIALS
卷 9, 期 -, 页码 -出版社
FRONTIERS MEDIA SA
DOI: 10.3389/fmats.2022.839421
关键词
pyrolysis; bio-char; activation; adsorption; activated carbon
This study proposes a method for converting waste corn grains contaminated by vomitoxin into value-added products. By pyrolysis and CO2 activation, activated bio-char with large surface area and pore volume can be obtained. The activated bio-char exhibits excellent adsorption performance, comparable to commercial activated carbon.
This study proposes the conversion of waste corn grains contaminated by deoxynivalenol (also known as vomitoxin), a mycotoxin produced by plant pathogens, into a value-added product. Batches of 500 g of contaminated corn grains were pyrolyzed in a batch reactor by thermal treatment at temperatures up to 500 degrees C with a 15 degrees C/min heating rate and generating condensable vapors, gases and solid bio-char. The bio-char produced was subsequently activated in a furnace at 900 degrees C, using CO2 as an activation agent, at different residence times. The effect of activation residence time on the characteristics of the activated bio-char, varying it from 0.5 to 3 h, was investigated. Characterization tests included BET surface area, SEM, TG-FTIR, pH, and XRD on both bio-char and activated bio-char. BET results illustrated a significant increase of the surface area from 63 to 419 m(2)g(-1) and pore volume from 0.04 to 0.23 cm(3)g(-1) by increasing the activation time from 0.5 to 3 h. SEM images visually confirmed a considerable increase in pore development. The pH significantly increased from 6 to 10 after activation, due to the elimination of acidic functional groups. The proximate analysis showed the stable carbon of the activated char reaching approximately 90 wt%, making it promising for catalyst/adsorbent applications. The adsorption performance of activated bio-char was tested by utilizing three different model molecules with different characteristics: methylene blue, methyl orange, and ibuprofen. Among all activated bio-char samples, activated bio-char with 3 h activation time showed the highest adsorption capacity, with a total adsorption (25 mg/g of activated bio-char) of methylene blue after 5 min. The results showed that the adsorption capacity of the activated bio-char was similar to that of valuable commercial activated carbon.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据