Synthesis of Novel Luminescent Double-Decker Silsesquioxanes Based on Partially Condensed TetraSilanolPhenyl POSS and Tb3+/Eu3+ Lanthanide Ions

In this study, novel lanthanide-containing double-decker polyhedral oligomeric silsesquioxanes (POSS) were prepared by combining the partially condensed TetraSilanolPhenyl POSS with terbium (Tb3+) and europium (Eu3+) ions. This open-cage POSS possesses four diametrically opposite silanol groups that are able to coordinate, under mild conditions, different luminescent ions through a simple corner-capping method. The two metal-containing POSS functionalized with Tb3+ and with an equimolar combination of Tb3+ and Eu3+ show a completely condensed structure with different luminescent properties. Their emission features depend on the chemical nature of the metal ions incorporated in the framework. An improved stokes shift was detected in the bimetallic compound containing both the Tb3+ and Eu3+ ions, promoted by the occurrence of a Tb3+-> Eu3+ energy transfer mechanism. These characteristics identify this metal-functionalized silica platform as a potential candidate for the development of novel luminescent devices.

Automated summary

This study successfully prepared a novel metal-functionalized silica platform with great potential for applications. This platform can coordinate with different luminescent ions through a simple method and exhibit different luminescent properties depending on the chemical nature of the metal ions. Particularly, the bimetallic compound containing Tb3+ and Eu3+ ions showed improved emission characteristics and Stokes shift.