期刊
SCIENCE ADVANCES
卷 8, 期 12, 页码 -出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/sciadv.abm3541
关键词
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资金
- National Key R&D Program of China [2017YFA0204901, 2021YFA1200101, 2018YFA0703700]
- National Natural Science Foundation of China [21727806, 21933001, 22173050, 22150013, 12034002, 51971025, 21772003, 22071004]
- Tencent Foundation through the XPLORER PRIZE
- Youth Innovation Promotion Association CAS [2019441]
- Frontiers Science Center for New Organic Matter at Nankai University [63181206]
In this study, we demonstrate two configurations of a graphene-porphyrin-graphene single-molecule junction (SMJ) driven by electric field and proton transfer. The transistor configuration shows exceptional field-effect performance with high on/off ratio and gate efficiency. The other configuration reveals controllable proton transfer and tautomerization switching. This work provides insights into constructing multifunctional molecular nanocircuits and understanding the intrinsic properties of matters at the molecular scale.
Single-molecule junctions (SMJs) offer a novel strategy for miniaturization of electronic devices. In this work, we realize a graphene-porphyrin-graphene SMJ driven by electric field and proton transfer in two configurations. In the transistor configuration with ionic liquid gating, an unprecedented field-effect performance is achieved with a maximum on/off ratio of similar to 4800 and a gate efficiency as high as similar to 179 mV/decade in consistence with the theoretical prediction. In the other configuration, controllable proton transfer, tautomerization switching, is directly observed with bias dependence. Room temperature proton transfer leads to a two-state conductance switching, and more precise tautomerization is detected, showing a four-state conductance switching at high bias voltages and low temperatures. Such an SMJ in two configurations provides new insights into not only building multifunctional molecular nanocircuits toward real applications but also deciphering the intrinsic properties of matters at the molecular scale.
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