期刊
CHEMISTRYSELECT
卷 7, 期 15, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202104581
关键词
Biocompatible; Cell imaging; DFT; Neutron diffraction; Upconversion Green phosphor
资金
- CSIR
- Scientific User Facilities Division, Office of Basic Energy Sciences, Department of Energy, US
- SSL (JNCASR)
In this study, we reported the synthesis, crystal structure, and upconversion emission of NaLa(WO4)(2): Yb3+/Er3+ in both bulk and nanomaterial forms. The host lattice dynamics of the disordered NaLa(WO4)(2) matrix were investigated using DFT and neutron diffraction studies, revealing the presence of phonons at a cut-off frequency of approximately 912 cm(-1). The optimized concentration of NaLa0.865Er0.035Yb0.1(WO4)(2), referred to as UCB and UCN, was obtained using a solvothermal method. High-resolution microscopy studies showed the existence of high-density edge dislocations in UCN nanomaterials, leading to enhanced phonon scattering. Both UCB and UCN materials exhibited intense pump power-dependent upconversion green emission under 980 nm laser irradiation. Furthermore, we demonstrated the non-toxicity of UCB and UCN towards bacterial and fungal strains, as well as their potential application in in vitro cell imaging. Overall, the neutron diffraction, DFT, microscopy, and spectroscopic analysis provided valuable insights into the structure-property relationship of these biocompatible upconversion green fluorescent bifunctional NaLa(WO4)(2) materials.
We report the synthesis, systematic crystal structure, and upconversion (UC) emission in bulk and nanomaterials of NaLa(WO4)(2): Yb3+/Er3+. The disordered NaLa(WO4)(2) matrix has been considered as the UC host and host lattice dynamics were investigated using DFT, and neutron diffraction studies. The presence of phonons at the cut-off frequency of similar to 912 cm(-1) is revealed by DFT analysis which is further confirmed by room temperature Raman studies. The optimized concentration of NaLa0.865Er0.035Yb0.1(WO4)(2) is referred to as UCB and UCN with respect to particle size derived from a facile solvothermal method. Interestingly, high-resolution microscopy studies uncovered the existence of high-density edge dislocations in UCN nanomaterials leading to enhanced phonon scattering. Both UCB and UCN materials have shown pump power-dependent intense UC green emission upon 980 nm laser irradiation. In addition, we have also demonstrated an excellent non-toxicity of UCB and UCN towards Escherichia coli, Staphylococcus aureus, Candida albicans, and mammalian HeLa cell lines followed by the potential use of nanomaterials for in vitro cell imaging. Thus, the combined neutron diffraction, DFT, microscopy, and spectroscopic analysis collectively resulted in the right structure-property relationship in these biocompatible UC green fluorescent bifunctional NaLa(WO4)(2) materials.
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