期刊
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
卷 18, 期 -, 页码 2413-2427出版社
ELSEVIER
DOI: 10.1016/j.jmrt.2022.03.131
关键词
Ramie; Fibers; Tannin-based polyurethane; Thermal stability; Mechanical properties
资金
- National Research and Innovation Agency of Indonesia (Pengembangan Serat Rami Tahan Api Terimpregnasi Resin Poliuretan Sebagai Bahan Baku Tekstil Fungsional)
- Slovak Research and Development Agency [APVV-18-0378, APVV-19-0269]
- Scientific Grant Agency of the Ministry of Education, Science, Research, and Sport of the Slovak Republic at the University of Forestry, Sofia, Bulgaria [VEGA 1/0714/21]
- University of Forestry, Sofia, Bulgaria [H.C-.-1145/04.2021]
This study aimed to develop a bio-based polyurethane resin derived from tannin and impregnate ramie fibers with the resin. The results showed that impregnation improved the thermal stability and mechanical properties of the fibers, enhancing their comprehensive industrial application as a functional material.
This study aimed to develop bio-based polyurethane (PU) resin derived from tannin for the impregnation process of ramie fibers (Boehmeria nivea L.) and to investigate the mechanical and thermal properties of impregnated fibers. Tannin was extracted from Acacia mangium bark using hot-water extraction. The polymeric diphenylmethane diisocyanate (pMDI) was added into tannin extract to prepare tannin-based PU (TPU) resin. Degummed ramie fibers were impregnated by TPU resins for 1, 2, and 3 h at a temperature of 25 degrees C under a pressure of 50 kPa in a vacuum chamber. The weight gain of fibers after impregnation increased by 73.26%. After the impregnation process, the formation of urethane linkages on fibers was detected by fourier-transform infrared spectroscopy (FTIR) and micro confocal Raman spectroscopy. Field emission scanning electron miscroscopy (FE-SEM) coupled with energy dispersive x-ray (EDX) detected the TPU on the surface of ramie fibers, indicating by increasing of Nitrogen content on ramie fibers which derived from TPU. Using thermogravimetric analysis (TGA), the thermal stability of fibers increased from 14.2% to 32.6% of weight residue after heating at 750 degrees C. In addition, x-ray diffractogram (XRD) analysis showed that impregnation process increased the crystallinity of ramie fibers, resulting in increased of modulus of elastictiy by maximum of 29.5% and tensile strength by 4.7%, respectively, after 1 h of impregnation time. This study demonstrated the positive effect of impregnating ramie fibers by TPU resin on their thermal and mechanical properties, enhancing their more comprehensive industrial application as a value-added functional material.(c) 2022 The Author(s). Published by Elsevier B.V.
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