期刊
CHEMNANOMAT
卷 8, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cnma.202200112
关键词
Polytypic nanocrystals; copper indium selenide; tetrapods; core; shell nanostructure; hollow nanostructure
资金
- National Natural Science Foundation of China [51902019, 52011530123]
- Beijing Natural Science Foundation [2222061]
- City University of Hong Kong [7005647]
This study presents a synthetic approach to produce polytypic CuInSe2 nanocrystals with variable morphologies, including tetrapods, core/shell structures, and hollow structures. These nanostructures consist of a chalcopyrite phase core and wurtzite phase arms or shells, and their size and morphology can be tuned by adjusting the nucleation temperature.
Despite the merits of low toxicity and light absorption/emission in the near-infrared spectral range, synthesis of polytypic CuInSe2 nanocrystals is challenging. Herein, we demonstrate a synthetic approach to produce polytypic CuInSe2 nanocrystals with variable morphologies, such as tetrapods with short or long arms; core/shell nanostructures; and hollow structures formed due to the Kirkendale effect. All polytypic CuInSe2 nanostructures realized in this work consist of a core with a chalcopyrite phase, and arms or shells with a wurtzite phase. With increasing nucleation temperature, the size of the chalcopyrite core gradually increases, while the arms or shells become smaller/thinner, due to the competition between nucleation and growth. This work provides guidance towards the synthesis of polytypic CuInSe2 nanocrystals with tunable size and morphology, and enriches the family of available CuInSe2 nanostructures.
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