4.7 Review

Advances in flexible lithium metal batteries

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Article Engineering, Environmental

A high ion-conducting, self-healing and nonflammable polymer electrolyte with dynamic imine bonds for dendrite-free lithium metal batteries

Kuirong Deng et al.

Summary: The novel polymer electrolyte PBPE with excellent self-healing capability has effectively enhanced the reliability and performance of batteries. The self-healed PBPE exhibits properties almost identical to the original PBPE, providing a solution to mechanical damage in batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Rational Design of Li-Wicking Hosts for Ultrafast Fabrication of Flexible and Stable Lithium Metal Anodes

Jian Chang et al.

Summary: This study introduces a highly scalable Li-wicking strategy for ultrafast fabrication of mechanically flexible and electrochemically stable Li metal anodes. The unique 3D Li metal structure formed through this strategy not only offers remarkable flexibility but also suppresses dendrite formation, leading to high energy density and excellent mechanical stability in flexible full cells.
Review Chemistry, Physical

Unlocking the Failure Mechanism of Solid State Lithium Metal Batteries

Jia Liu et al.

Summary: Solid-state lithium metal batteries are considered the ultimate choice for future energy storage systems due to their high theoretical energy density and safety features. However, practical applications are hindered by severe interfacial issues. Understanding the failure mechanisms is crucial for constructing safer solid-state lithium batteries.

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Article Chemistry, Multidisciplinary

Artificial Skin Perception

Ming Wang et al.

Summary: Electronic skin (e-skin) replicates human skin to achieve artificial sensation through flexible and stretchable electronic components. While progress has been made in data collection and transmission, the perception functionality is still in its early stage. Integrating perception into flexible sensing systems, artificial skin perception is crucial for endowing systems with higher intelligence.

ADVANCED MATERIALS (2021)

Review Chemistry, Physical

Fibrous Materials for Flexible Li-S Battery

Yuan Gao et al.

Summary: Fibrous materials show promising prospects for achieving high-energy-density flexible Li-S batteries due to their intrinsic flexibility, lightweight, large surface area, and cost-effectiveness. These materials can be suitable for constructing various battery components and offer good tunability of structure and function. The review focuses on recent developments in fibrous materials for flexible Li-S batteries, with an emphasis on material synthesis, design of fibrous structures and functionalities, and battery cell layout for achieving high Coulombic efficiency, long cycle life, and good flexibility.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Superstretchable, thermostable and ultrahigh-loading lithium-sulfur batteries based on nanostructural gel cathodes and gel electrolytes

Wen Yan et al.

Summary: The study demonstrates the fabrication of superstretchable Li-S batteries based on highly elastic gel cathodes, gel electrolytes, zigzag Cu wire-interconnected Li anode pieces and soft packages. The gel cathodes with tri-continuous structures and gel electrolytes with high ionic conductivity and thermal stability show effective suppression of Li dendrite growth and allow the batteries to be stretched up to 420% of their original length, function at high temperatures and deliver ultrahigh areal capacity.

NANO ENERGY (2021)

Article Chemistry, Physical

In situ formation of poly(butyl acrylate)-based non-flammable elastic quasi-solid electrolyte for dendrite-free flexible lithium metal batteries with long cycle life for wearable devices

Guodong Zhou et al.

Summary: A newly developed non-flammable elastic quasi-solid electrolyte has shown excellent stability and high capacity retention in lithium metal batteries, making it promising for the application in next-generation wearable devices.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

An Ultra-Long-Life Flexible Lithium-Sulfur Battery with Lithium Cloth Anode and Polysulfone-Functionalized Separator

Baozhi Yu et al.

Summary: By utilizing stable lithium cloth anodes, polysulfone-functionalized separators, and sulfur/graphene/boron nitride nanosheet cathodes, the shuttle effect of polysulfides and the growth of lithium dendrites have been effectively controlled, leading to excellent mechanical flexibility and outstanding electrochemical performance in flexible lithium-sulfur batteries, indicating great potential for large-scale development of high-performance flexible batteries.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

Constructing Electronic and Ionic Dual Conductive Polymeric Interface in the Cathode for High-Energy-Density Solid-State Batteries

Hao Li et al.

Summary: The study on the application of electronic and ionic dual conductive polymer in the composite cathode for solid-state batteries shows that through crosslinking, coordination, and hydrogen-bonding effect, the polymer achieves high electrical conductivity and high modulus, forming a coating layer to maintain structural integrity of active material powders and enabling excellent cycling performance of solid-state batteries with high loading and high active material content.

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Interface covalent bonding endowing high-sulfur-loading paper cathode with robustness for energy-dense, compact and foldable lithium-sulfur batteries

Hong Li et al.

Summary: This study demonstrates the design of densely-packed graphene/CoS2/nano-sulfur hybrid papers through interface covalent bonding, achieving high-density, compact, and foldable lithium-sulfur batteries. The batteries show high cycling stability and energy density, suitable for flexible power systems.

CHEMICAL ENGINEERING JOURNAL (2021)

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The 2021 battery technology roadmap

Jianmin Ma et al.

Summary: The article discusses the potential of solar, wind, and tidal energy in providing electricity, as well as the role of energy storage technology in addressing challenges in renewable energy generation. Research focus on battery technology includes various types of batteries and their related materials, as well as the flexibility of battery construction.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2021)

Article Chemistry, Multidisciplinary

Deep Cycling for High-Capacity Li-Ion Batteries

Huarong Xia et al.

Summary: A new deep-cycling architecture has been developed to break the theoretical capacity limit of conventional Li-ion batteries, which offers higher capacity and energy storage efficiency by utilizing movable ions in both electrolyte and electrodes. This architecture shows 57.7% more capacity and 84.4% retention after 2000 cycles, indicating its potential for next-generation energy storage devices.

ADVANCED MATERIALS (2021)

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Stamping Flexible Li Alloy Anodes

Jinlong Gao et al.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Pathways of Developing High-Energy-Density Flexible Lithium Batteries

Jian Chang et al.

Summary: This article discusses the importance of the future development of FLBs, including achieving high energy density and high flexibility. It summarizes the industrial criteria of FLBs in flexible and wearable electronics applications, as well as strategies to achieve flexibility of FLBs and representative examples.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Cation-Assisted Lithium-Ion Transport for High-Performance PEO-based Ternary Solid Polymer Electrolytes

Jaschar Atik et al.

Summary: The study demonstrates that incorporating a pyrrolidinium cation with an oligo(ethylene oxide) substituent in SPEs can enhance lithium-ion transport speed. This not only accelerates the conduction modes of PEO, but also enables new conduction modes associated with the solvation of lithium by a single IL cation, leading to improved performance on lithium-metal polymer batteries.

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Article Chemistry, Multidisciplinary

Preparation of fully flexible lithium metal batteries with free-standing β-Na0.33V2O5 cathodes and LAGP hybrid solid electrolytes

Jong Su Han et al.

Summary: This study introduces a new manufacturing method for flexible batteries with metal-free current collectors, successfully integrating them into flexible lithium metal batteries, and enhancing high temperature stability and safety characteristics with a hybrid solid electrolyte. The result is fast and stable lithium-ion storage capabilities with excellent cycling performance.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2021)

Article Chemistry, Physical

Pouch-type hybrid Li-air battery enabled by flexible composite lithium-ion conducting membrane

Shao-Hao Lu et al.

Summary: The use of a flexible composite lithium-ion conducting membrane enables the realization of a flexible pouch-type hybrid Li-air battery, overcoming the difficulties of assembling traditional Li-air batteries into flexible devices.

JOURNAL OF POWER SOURCES (2021)

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Functional polymers for lithium metal batteries

Sipei Li et al.

Summary: This review article discusses recent advances in using functional polymer materials to improve the stability of Li metal batteries (LMBs), emphasizing the crucial role of designing and implementing functional polymers in enhancing the practical performance and commercialization of LMBs.

PROGRESS IN POLYMER SCIENCE (2021)

Review Chemistry, Physical

Single-Ion Conducting Polymer Electrolytes for Solid-State Lithium-Metal Batteries: Design, Performance, and Challenges

Jiadeng Zhu et al.

Summary: This paper summarizes the advantages of single-ion conducting polymer electrolytes as solid electrolytes, including their potential in realizing solid-state lithium batteries, reducing the buildup of ion concentration gradients, and suppressing the growth of lithium dendrites. It also discusses current challenges, possible solutions, and future research directions.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Realizing High-Energy and Stable Wire-Type Batteries with Flexible Lithium-Metal Composite Yarns

Yuan Gao et al.

Summary: Flexible and stable Li-metal composite yarn (LMCY) is designed for high-energy-density and long-lasting wire-type Li-metal batteries, showing outstanding performance. Pairing with lithium-iron phosphate (LFP) can deliver high energy density and long lifetime in a foldable full cell configuration.

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A Flexible Li-Air Battery Workable under Harsh Conditions Based on an Integrated Structure: A Composite Lithium Anode Encased in a Gel Electrolyte

Jiajie Li et al.

Summary: The researchers designed an innovative configuration for lithium-air batteries, utilizing a 3D open-structured cathode and a composite lithium anode encased in a gel electrolyte to achieve stable operation in high humidity environments. This battery can achieve over 100 stable cycles and remains operational under extreme conditions, demonstrating great potential for flexible electronics applications.

ACS APPLIED MATERIALS & INTERFACES (2021)

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10 μm-Thick High-Strength Solid Polymer Electrolytes with Excellent Interface Compatibility for Flexible All-Solid-State Lithium-Metal Batteries

Zhiyan Wang et al.

Summary: This study presents an ultrathin solid polymer electrolyte with high ionic conductance and excellent mechanical properties, showing promising stability in various battery systems, particularly in all-solid-state lithium-metal batteries.

ADVANCED MATERIALS (2021)

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Designing Polymer-in-Salt Electrolyte and Fully Infiltrated 3D Electrode for Integrated Solid-State Lithium Batteries

Wenyi Liu et al.

Summary: A solid-state lithium battery with high room-temperature ionic conductivity was designed, achieving faster Li+ transport and superior electrochemical performance through the construction of an integrated model SSLB.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Multi-scale uniform Li regulation triggered by tunable electric field distribution on oxygen-functionalized porous framework for flexible Li-S full batteries

Yue Ouyang et al.

Summary: This study presents an oxygen-functionalized mesoporous carbon nanofiber framework for dendrite-free lithium metal anode and stable sulfur cathode in Li-S batteries. The flexible Li-S full battery exhibits remarkable electrochemical performance with high rate capability and low capacity decay rate, paving the way for practical applications in flexible energy storage devices.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Nanophase-Separated, Elastic Epoxy Composite Thin Film as an Electrolyte for Stable Lithium Metal Batteries

Ziqi Zeng et al.

Summary: A reaction-controlled strategy based on nanophase separation was used to synthesize an elastic epoxy polymer electrolyte with both high ionic conductivity and excellent mechanical properties. This electrolyte promotes uniform deposition of lithium and greatly improves the safety performance of LiFePO4/Li pouch cells under various abusive conditions, highlighting an alternative route for high-safety solid-state lithium metal batteries of the next generation.

NANO LETTERS (2021)

Article Multidisciplinary Sciences

A highly stable and flexible zeolite electrolyte solid-state Li-air battery

Xiwen Chi et al.

Summary: Solid-state lithium-air batteries with integrated ultrathin, high-ion-conductive zeolite X membrane as the sole solid electrolyte exhibit excellent electrochemical performance, flexibility, and stability. These batteries have a high capacity and cycle life, outperforming batteries based on other materials under the same conditions, and show potential for practical applicability in various energy-storage systems.

NATURE (2021)

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A dynamic stability design strategy for lithium metal solid state batteries

Luhan Ye et al.

Summary: A multi-layered electrolyte design can inhibit the growth of lithium dendrites in solid-state lithium metal batteries, improving their performance. However, practical challenges remain in realizing a lithium metal anode for batteries.

NATURE (2021)

Article Chemistry, Physical

Ultrahigh-Energy-Density Flexible Lithium-Metal Full Cells based on Conductive Fibrous Skeletons

Seung-Hyeok Kim et al.

Summary: This study introduces a new electrode architecture strategy based on conductive fibrous skeletons, achieving high performance and mechanical flexibility of LMBs by embedding lithium and over-lithiated layered oxide into conductive fibers.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Flexible Nanocomposite Polymer Electrolyte Based on UV-Cured Polyurethane Acrylate for Lithium Metal Batteries

Qian Wu et al.

Summary: Commercial organic liquid electrolytes face safety challenges in lithium metal batteries, while nanocomposite polymer electrolytes (NCPEs) can provide both safety enhancement and separator functions. A novel NCPE-4 with in situ TiO2 nanoparticles and ionic liquid as a plasticizer shows high ionic conductivity, stable interface compatibility, and improved electrochemical stability, making it a promising candidate for practical applications in lithium metal batteries.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Chemistry, Physical

Straightforward strategy toward a shape-deformable carbon-free cathode for flexible Li?air batteries in ambient air

Ji-Won Jung et al.

Summary: A novel strategic approach was reported for fabricating a large-area carbon-free cathode for shape-deformable F-LABs, which showed excellent stability under dynamic deformation modes in ambient air. The flexible cathode, consisting of metallic iridium and IrOx layers deposited on porous, flexible polyimide nanofibers, exhibited superior electrochemical characteristics and stability in both pure O2 and dry-air atmospheres. Additionally, the F-LAB cells using this cathode demonstrated practical operation in small devices for the first time.

NANO ENERGY (2021)

Article Chemistry, Multidisciplinary

A Stretchable and Safe Polymer Electrolyte with a Protecting-Layer Strategy for Solid-State Lithium Metal Batteries

Shengzhao Zhang et al.

Summary: The newly prepared stretchable solid electrolyte has ultrahigh elongation, nonflammability, and high ionic conductivity, while forming a tougher and more stable SEI on the anode. LiFePO4/Li cells employing this electrolyte exhibit excellent cycling performance, and the flexible battery based on it can operate in various deformed states.

ADVANCED SCIENCE (2021)

Review Engineering, Environmental

Challenges and progresses of lithium-metal batteries

Jinming Wang et al.

Summary: Lithium-metal batteries are seen as promising candidates for high energy density storage devices, but face challenges such as reactive lithium, dendrite growth, and unstable interfaces. This review discusses strategies to address these challenges through modifications to battery components and external conditions, aiming to provide new insights for commercial applications of high-performance LMBs.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Flexible free-standing cathode enabled via multifunctional Mo2C for high sulfur loading lithium-sulfur batteries

Yuqiong Mao et al.

Summary: The Mo2C/CC host material designed for lithium-sulfur batteries exhibits excellent conductivity, large internal space, and the ability to inhibit the shuttle effect of lithium polysulfides. This results in impressive specific capacity and long-term cyclability for the sulfur cathodes based on this host material. Furthermore, the 3D nanoarrays structure of Mo2C/CC enables high capacity with a high sulfur loading and steady cycling in pouch cells.

JOURNAL OF POWER SOURCES (2021)

Article Chemistry, Multidisciplinary

Electrocatalytic NiCo2O4 Nanofiber Arrays on Carbon Cloth for Flexible and High-Loading Lithium-Sulfur Batteries

Shaojie Chen et al.

Summary: Lithium-sulfur batteries have high theoretical energy densities, but face challenges in large-scale commercialization due to the sulfur polysulfide shuttle effect and low sulfur loading. This study demonstrates a flexible lithium-sulfur battery with high sulfur loading using NiCo2O4 nanofiber array grown carbon cloth, achieving good cycle stability.

NANO LETTERS (2021)

Article Chemistry, Multidisciplinary

High Performance Air Breathing Flexible Lithium-Air Battery

Ahmad Jaradat et al.

Summary: A cost-effective, flexible, and wearable Li-O-2 battery has been designed in this study, which can operate in pure oxygen, dry air, and ambient air. The battery demonstrates excellent cycling and electrochemical performance, showing potential for applications in flexible and wearable electronics.
Review Chemistry, Physical

A review of self-healing electrode and electrolyte materials and their mitigating degradation of Lithium batteries

Ejikeme Raphael Ezeigwe et al.

Summary: This paper reviews the use of self-healing materials in electrochemical energy storage devices and analyzes the technical challenges encountered in practical applications. The research finds that self-healing ability can effectively prolong the lifespan of lithium batteries, providing new insights for future research and development.

NANO ENERGY (2021)

Review Chemistry, Physical

Recent progress of flexible/wearable self-charging power units based on triboelectric nanogenerators

Wen He et al.

Summary: This review article presents the recent progress of flexible TENG-based self-charging power units (SCPUs), including working modes, research progress, strategies to improve energy conversion efficiency, as well as highlighting the main challenges that need to be overcome when designing and optimizing TENG-based SCPUs.

NANO ENERGY (2021)

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Anion-Doped Cobalt Selenide with Porous Architecture for High-Rate and Flexible Lithium-Sulfur Batteries

Tao Feng et al.

Summary: The proposed method of synthesizing Co0.85Se electrocatalyst with macroporous architecture and S-doping effectively improves the electrocatalytic performance of lithium-sulfur batteries, achieving high initial capacity and stable cycling capacity. Additionally, the in situ synthesis of Co0.85SeS on flexible carbon cloth facilitates high sulfur loading and maintains reversible capacity even at high current densities, showing promise for high-rate and flexible Li-S batteries.

SMALL METHODS (2021)

Article Chemistry, Physical

Uniformly Dispersed Ru Nanoparticles Constructed by In Situ Confined Polymerization of Ionic Liquids for the Electrocatalytic Hydrogen Evolution Reaction

Yong-Ya Zhang et al.

Summary: By utilizing divinyl functionalized ionic liquids, Ru nanoparticles supported on nitrogen-doped carbon frameworks were synthesized, showing excellent stability and efficiency for hydrogen production via water splitting. The optimized catalyst exhibited low overpotential and Tafel slope, and maintained stability even after 10,000 cycles, demonstrating promising industrial applications. This work not only presents a facile method for preparing efficient Ru-based catalysts, but also provides insights for synthesizing highly dispersed metallic nanoparticles for specific applications.

SMALL METHODS (2021)

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Laser-Ablated Red Phosphorus on Carbon Nanotube Film for Accelerating Polysulfide Conversion toward High-Performance and Flexible Lithium-Sulfur Batteries

Jeongyeon Lee et al.

Summary: The use of a red phosphorus nanoparticle-coated carbon nanotube film as an interlayer in Li-S batteries shows promise in enhancing performance by trapping lithium polysulfides. The interlayer provides pathways for effective Li+ and electron transfer and exhibits strong chemical interactions with LiPSs, resulting in superior specific capacity and cycling performances. This work demonstrates the potential of using this interlayer for improved electrochemical performances in Li-S batteries and other flexible energy storage devices.

SMALL METHODS (2021)

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In Situ Generated Mixed Ion/Electron-Conducting Scaffold with Uniform Li Deposition for Flexible Li Metal Anodes

Yueli Cheng et al.

Summary: In this study, a mixed ion/electron-conducting scaffold (MIECS) was developed as a flexible Li metal anode host, which achieved uniform Li nucleation and growth by converting Cu2S into a high Li-ion-conductive Li2S layer. The MIECS demonstrated enhanced electrochemical performances and high flexibility.

ACS APPLIED ENERGY MATERIALS (2021)

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Highly stretchable, non-flammable and notch-insensitive intrinsic self-healing solid-state polymer electrolyte for stable and safe flexible lithium batteries

Cheng Wang et al.

Summary: A highly stretchable, non-flammable, and notch-insensitive solid-state polymer electrolyte with prominent self-healing ability was prepared, showing excellent performance in lithium batteries. The incorporation of imidazole cation and fluorine atom contributed to the formation of supramolecular bonds, while DFT calculations indicated a superior electrostatic attraction for Li+ towards SO3-. The optimized SHSPE3 demonstrated good interfacial compatibility with lithium electrodes and high adhesion strength, delivering a high discharge capacity and excellent cycling performance in LiFePO4 batteries. The use of intrinsic self-healing principles in SPEs provides new insights for developing reliable and safe flexible electronic devices.

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Highly-dispersed Ge quantum dots in carbon frameworks for ultra-long-life sodium ion batteries

Wei Wei et al.

Summary: A new in situ confined polymerization method was proposed for preparing highly dispersed Ge quantum dots to address the agglomeration problem in sodium ion batteries. The obtained Ge@C nanocomposite showed ultra-long cycle life and high rate capability when used as the anode material.

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Xijian Liu et al.

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Phosphorus-sulfur/graphene composites as flexible lithium-sulfur battery cathodes with super high volumetric capacity

Cheng-Chieh Chuang et al.

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Jian Chang et al.

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Yang Li et al.

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Surface Mechanism of Catalytic Electrodes in Lithium-Oxygen Batteries: How Nanostructures Mediate the Interfacial Reactions

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Dong Zhou et al.

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An Illumination-Assisted Flexible Self-Powered Energy System Based on a Li-O2 Battery

Xiao-yang Yang et al.

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Self-Healable Solid Polymeric Electrolytes for Stable and Flexible Lithium Metal Batteries

Na Wu et al.

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Protecting the Lithium Metal Anode for a Safe Flexible Lithium-Air Battery in Ambient Air

Tong Liu et al.

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A Quasi-Solid-State Flexible Fiber-Shaped Li-CO2 Battery with Low Overpotential and High Energy Efficiency

Jingwen Zhou et al.

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Freestanding Carbon Nanotube Film for Flexible Straplike Lithium/Sulfur Batteries

Xiaoyu Ding et al.

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Elastic, plastic, and creep mechanical properties of lithium metal

Alvaro Masias et al.

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Swelling Poly(ionic liquid) Supported by Three-Dimensional Wire Mesh for Oil/Water Separation

Yongya Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Flexible S/DPAN/KB Nanofiber Composite as Binder-Free Cathodes for Li-S Batteries

Sandugash Kalybekkyzy et al.

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Stretchable fiber-shaped lithium metal anode

Xianshu Wang et al.

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Tribute to Michel Armand: from Rocking Chair - Li-ion to Solid-State Lithium Batteries

Alain Mauger et al.

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A Material Perspective of Rechargeable Metallic Lithium Anodes

Bin Li et al.

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A flexible polymer-based Li-air battery using a reduced graphene oxide/Li composite anode

Ziyang Guo et al.

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Flexible Lithium-Air Battery in Ambient Air with an InSitu Formed Gel Electrolyte

Xiaofeng Lei et al.

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Self-Healing Polymer Electrolytes Formed via Dual-Networks: A New Strategy for Flexible Lithium Metal Batteries

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Flexible and stable high-energy lithium-sulfur full batteries with only 100% oversized lithium

Jian Chang et al.

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Bending-Tolerant Anodes for Lithium-Metal Batteries

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A Li-Air Battery with Ultralong Cycle Life in Ambient Air

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Lithium-Sulfur Battery Cable Made from Ultralight, Flexible Graphene/Carbon Nanotube/Sulfur Composite Fibers

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Ultrathin CuCo2O4 Nanosheets on Carbon Textiles as Flexible Cathodes for Bendable Lithium-Air Batteries

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An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes

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