4.6 Article

Enhanced Li+ Ionic Conduction and Relaxation Properties of Li5+2xLa3Ta2-xGaxO12 Garnets

期刊

CRYSTALS
卷 12, 期 6, 页码 -

出版社

MDPI
DOI: 10.3390/cryst12060770

关键词

lithium conducting garnets; ionic conduction; conductivity relaxation; dielectric properties

资金

  1. Deanship of Scientific Research in King Faisal University (Saudi Arabia) [1811017]

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In this study, we investigated the effect of Ga+3 substitutions on the Ta+5 sites in LLT-Ga lithium conducting garnets in order to enhance their ionic conductivity. The results showed that the concentration and mobility of Li+ ions increased with increasing Ga+3 content in the materials.
In the current work, we studied the effect of Ga+3 substitutions on the Ta+5 sites in Li5+2xLa3Ta2-xGaxO12 (LLT-Ga) lithium conducting garnets (with x = 0.1-0.5) in order to enhance the ionic conductivity of these materials. The current materials are prepared by solid state reaction and their electrical properties are studied by impedance spectroscopy measurements. XRD data showed that cubic garnet phases are obtained for LLT-Ga garnets. The ionic conductivity increased by one order of magnitude for x = 0.3 composition with a value of similar to 4 x 10(-5) S/cm compared to that of Li5La3Ta2O12 material. Moreover, the hopping frequency and the concentration of mobile Li+ ions were estimated from analysis of the conductivity spectra, and it was found that both the concentration and mobility of Li+ ions increased with increasing Ga+3 content in the materials. The dielectric and relaxation properties were studied in the dielectric permittivity and electric modulus formalisms. The current materials exhibited giant values of the dielectric constant of epsilon'similar to 6500, originating from internal effects in the materials.

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