期刊
NANOMATERIALS
卷 12, 期 8, 页码 -出版社
MDPI
DOI: 10.3390/nano12081354
关键词
Al alloy; plasma electrolysis; densification; hydrolysis; corrosion; frontier molecular orbital
类别
资金
- National Research Foundation of Korea (NRF) - Korean government (MSIT) [NRF-2022R1A2C1006743]
By adding sodium citrate into the electrolyte, the formation of a high-density alumina layer with high chemical stability was controlled successfully. Experimental results showed that the oxide layer obtained from the electrolyte with 5 g/L sodium citrate exhibited the highest chemical stability in a corrosive solution.
In this work, a high-density alumina layer with high chemical stability was successfully developed by controlling the hydrolysis of hexafluorosilicate (SiF62-) anions through the addition of various concentrations of sodium citrate (SCi) into the electrolyte of plasma electrolysis (PE). To achieve this aim, the substrate samples were anodized in alkaline aluminate-SiF62--based electrolytes with 0, 5, and 10 g/L of SCi. The presence of SCi anions in the electrolyte led to the formation of a thick adsorbed electrochemical double layer (EDL) on the substrate surface. The EDL not only affected the movement of SiF62- anions towards the anode but also influenced their hydrolysis reaction, which in turn led to a controllable sealing of structural defects with the hydrolysis products, namely SiO2 and AlF3. Among three different oxide layers, the oxide layer obtained from the electrolyte with 5 g/L SCi showed the highest chemical stability in a corrosive solution, which was linked to the fact that a considerable increase in the compactness of the oxide layers was obtained by the incorporation of SiO2 and AlF3. The mechanism underlying the effects of SCi on triggering the hydrolysis of SiF62- anions and factors affecting chemical stability are discussed based on the experimental data and computational analysis.
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