Flexible Cu3(HHTP)2 MOF Membranes for Gas Sensing Application at Room Temperature

Mixed matrix membranes (MMMs), possessing high porosity, have received extensive attention for gas sensing applications. However, those with high flexibility and significant sensitivity are rare. In this work, we report on the fabrication of a novel membrane, using Cu-3(HHTP)(2) MOF (Cu-MOF) embedded in a polymer matrix. A solution comprising a homogenous suspension of poly-vinyl alcohol (PVA) and ionic liquid (IL), and Cu-MOF solid particles, was cast onto a petri dish to obtain a flexible membrane (215 mu m in thickness). The sensor membrane (Cu-MOF/PVA/IL), characterized for its structure and morphology, was assessed for its performance in sensing against various test gases. A detection limit of 1 ppm at 23 degrees C (room temperature) for H2S was achieved, with a response time of 12 s. Moreover, (Cu-MOF/PVA/IL) sensor exhibited excellent repeatability, long-term stability, and selectivity towards H2S gas. The other characteristics of the (Cu-MOF/PVA/IL) sensor include high flexibility, low cost, low-power consumption, and easy fabrication technique, which nominate this sensor as a potential candidate for use in practical industrial applications.

Automated summary

The study introduces a novel mixed matrix membrane (Cu-MOF/PVA/IL sensor) with high flexibility and significant sensitivity for gas sensing applications. The sensor showed excellent performance in detecting H2S gas with a detection limit of 1 ppm at room temperature, along with great repeatability, long-term stability, and selectivity. The sensor also features high flexibility, low cost, low-power consumption, and easy fabrication technique, making it a potential candidate for practical industrial applications.