4.7 Article

Reversible Diels-Alder Addition to Fullerenes: A Study of Dimethylanthracene with H2@C60

期刊

NANOMATERIALS
卷 12, 期 10, 页码 -

出版社

MDPI
DOI: 10.3390/nano12101667

关键词

H-1 NMR spectroscopy; Diels-Alder reaction; 9; 10-dimethylanthracene; fullerene; H-2@C-60

资金

  1. National Natural Science Foundation of China [21975288]
  2. Hunan Reaserch Founding [2020JJ4683]
  3. Changsha Research Founding [2014121]
  4. Shenzhen Research Founding [JCYJ20190806144616528]

向作者/读者索取更多资源

The study investigates the unique environment provided by studying isolated atoms or molecules within a fullerene cavity. The research focuses on the Diels-Alder addition reaction between 9,10-dimethyl anthracene and H-2@C-60, and characterizes the reaction using H-1 NMR spectroscopy.
The study of isolated atoms or molecules inside a fullerene cavity provides a unique environment. It is likely to control the outer carbon cage and study the isolated species when molecules or atoms are trapped inside a fullerene. We report the Diels-Alder addition reaction of 9,10-dimethyl anthracene (DMA) to H-2@C-60 while H-1 NMR spectroscopy is utilized to characterize the Diels-Alder reaction of the DMA with the fullerene. Through H-1 NMR spectroscopy, a series of isomeric adducts are identified. The obtained peaks are sharp, precise, and straightforward. Moreover, in this paper, H-2@C-60 and its isomers are described for the first time.

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