期刊
NANOMATERIALS
卷 12, 期 10, 页码 -出版社
MDPI
DOI: 10.3390/nano12101667
关键词
H-1 NMR spectroscopy; Diels-Alder reaction; 9; 10-dimethylanthracene; fullerene; H-2@C-60
类别
资金
- National Natural Science Foundation of China [21975288]
- Hunan Reaserch Founding [2020JJ4683]
- Changsha Research Founding [2014121]
- Shenzhen Research Founding [JCYJ20190806144616528]
The study investigates the unique environment provided by studying isolated atoms or molecules within a fullerene cavity. The research focuses on the Diels-Alder addition reaction between 9,10-dimethyl anthracene and H-2@C-60, and characterizes the reaction using H-1 NMR spectroscopy.
The study of isolated atoms or molecules inside a fullerene cavity provides a unique environment. It is likely to control the outer carbon cage and study the isolated species when molecules or atoms are trapped inside a fullerene. We report the Diels-Alder addition reaction of 9,10-dimethyl anthracene (DMA) to H-2@C-60 while H-1 NMR spectroscopy is utilized to characterize the Diels-Alder reaction of the DMA with the fullerene. Through H-1 NMR spectroscopy, a series of isomeric adducts are identified. The obtained peaks are sharp, precise, and straightforward. Moreover, in this paper, H-2@C-60 and its isomers are described for the first time.
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