Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions

The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylate-based magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.

Automated summary

The increasing demand for precious and rare earth elements due to industrialization and urbanization expansion has raised the need for efficient methods to remove heavy metals from wastewaters and aqueous solutions. Adsorption is considered the most efficient technique, with methacrylate-based magnetic and non-magnetic porous sorbents being particularly attractive. This review discusses the main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics, and regeneration of polymeric sorbents.