期刊
CATALYSTS
卷 12, 期 4, 页码 -出版社
MDPI
DOI: 10.3390/catal12040360
关键词
biomass; carbohydrates; 2; 5-diformylfuran; fructose; glucose
资金
- Carbon to X Program [2020M3H7A1098283]
- Ministry of Science and ICT, Korea and Basic Science Research Program through the National Research Foundation of Korea - Ministry of Education [NRF-2021R1A6A1A10044950]
- National Research Foundation of Korea [2020M3H7A1098283, 2021R1A6A1A10044950]
- National Research Foundation of Korea [2020M3H7A1098283, 2021R1A6A1A10044950] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Versatile homogeneous and heterogeneous catalysts are crucial for the sustainable conversion of carbohydrates into high-value chemicals such as DFF. This study presents an efficient catalytic system consisting of Br-, disulfide, and DMSO that enables the selective synthesis of DFF from various carbohydrates. Heterogeneous catalysts containing Br- also show promising results with recyclable high yields.
Versatile homogeneous and heterogeneous catalysts that convert carbohydrates to 2,5-diformylfuran (DFF) are essential for the development of sustainable processes for producing high-value chemicals from biomass-derived carbohydrates. An efficient catalytic system consisting of Br-, disulfide, and dimethylsulfoxide (DMSO) promoted the sustainable and selective synthesis of DFF in modest-to-good yields from various carbohydrates, such as fructose, glucose, mannose, galactose, and sucrose. Heterogeneous catalysts containing Br- also facilitated this reaction with recyclable high yields.
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