期刊
ACS PHOTONICS
卷 9, 期 4, 页码 1206-1217出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsphotonics.1c01668
关键词
ultrathin photovoltaics; light trapping; hyperuniform correlated
类别
资金
- EPSRC [EP/P033431, EP/M013812, EP/M027961]
- University of Surrey's IAA awards
- EPSRC (United Kingdom) [EP/M027791/1, EP/N509772/1]
- EPSRC (United Kingdom) Strategic Equipment Grant [EP/L02263X/1, EP/M008576/1]
This study presents a new surface texturing technique for improving the absorption and efficiency of thin crystalline silicon solar cells. By using hyperuniform nanostructuring, it achieves a high solar light absorption of 66.5% in the spectral range of 400 to 1050 nm. This technology has the potential to increase the cell efficiency to above 15%.
Thin, flexible, and invisible solar cells will be a ubiquitous technology in the near future. Ultrathin crystalline silicon (c-Si) cells capitalize on the success of bulk silicon cells while being lightweight and mechanically flexible, but suffer from poor absorption and efficiency. Here we present a new family of surface texturing, based on correlated disordered hyperuniform patterns, capable of efficiently coupling the incident spectrum into the silicon slab optical modes. We experimentally demonstrate 66.5% solar light absorption in free-standing 1 mu m c-Si layers by hyperuniform nanostructuring for the spectral range of 400 to 1050 nm. The absorption equivalent photocurrent derived from our measurements is 26.3 mA/cm(2), which is far above the highest found in literature for Si of similar thickness. Considering state-of-the-art Si PV technologies, we estimate that the enhanced light trapping can result in a cell efficiency above 15%. The light absorption can potentially be increased up to 33.8 mA/cm(2) by incorporating a back-reflector and improved antireflection, for which we estimate a photovoltaic efficiency above 21% for 1 mu m thick Si cells.
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