4.5 Review

Recent Advances in Light-Induced Carboxylation of Organic (Pseudo)Halides with CO2

期刊

ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 11, 期 8, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202200207

关键词

carbon dioxide; carboxylation; photocatalysis; (pseudo)halides; carboxylic acids

资金

  1. National Natural Science Foundation of China [21871163, 22071134]

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This minireview summarizes the recent development in light-induced carboxylation of organic (pseudo)halides and analogues with CO2 via C-X (X=Br, Cl, O, N, etc.) bond cleavage.
Carbon dioxide is an ideal C1 source in organic synthesis as a precursor for the carboxyl group. With the development of photocatalysis, the carboxylation reactions with CO2 incorporation could be carried out in a more environmental and sustainable manner without the addition of stoichiometric metallic reductants. This minireview summarizes the recent development in light-induced carboxylation of organic (pseudo)halides and analogues with CO2 via C-X (X=Br, Cl, O, N, etc.) bond cleavage.

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