4.6 Article

Reaction Selectivity in Electro-oxidation of Lignin Dimer Model Compounds and Synthetic Lignin with Different Mediators for the Laccase Mediator System (PZH, NHPI, ABTS)

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 10, 期 20, 页码 6633-6641

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c00432

关键词

ABTS; Electrolytic mediator system; Electro-oxidation; Lignin; NHPI; Mediator; PZH

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This study investigated the electro-oxidation of lignin dimer model compounds and synthetic lignin in the presence of different mediators previously used in the laccase mediator system. The three mediators were found to effectively mediate the electro-oxidation reaction, although they showed different reaction selectivities towards different lignin linkages.
Electro-oxidation of lignin dimer model compounds bearing beta-O-4, beta-5, and beta-beta linkages and synthetic lignin (guaiacyl-type dehydrogenation polymer [G-DHP]) in the presence of different mediators previously used in the laccase mediator system (LMS), that is, promazine hydrochloride (PZH), N-hydroxyphthalimide (NHPI), and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), was investigated. The characteristics of the electro-oxidations of the lignin dimer model compounds were reflected in the electro-oxidation of G-DHP. The three mediators effectively mediated the electro-oxidation of G-DHP, although they showed different reaction selectivities toward the three major lignin linkages of G-DHP. Specifically, PZH preferentially mediated the oxidation of beta-O-4 and beta-beta linkages over beta-5 linkages, NHPI preferred beta-O-4 linkages over beta-5 and beta-beta linkages, and ABTS preferred beta-O-4 and beta-beta linkages over beta-5 linkages under the present conditions. NHPI and ABTS tended to mediate C alpha-C beta cleavage in contrast to PZH, and the three mediators all mediated the conversion of coniferyl alcohol end-units. Consequently, PZH, NHPI, and ABTS were found to be promising mediators for the electrolytic mediator system of lignin.

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