期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 10, 期 21, 页码 6871-6888出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c00873
关键词
C-H Functionalization; Ruthenium; Water; Micelles; Industry
资金
- ERC [101021358]
- DFG
- DAAD Reinvitation Programme
- Chinese Scholarship Council
- European Research Council (ERC) [101021358] Funding Source: European Research Council (ERC)
Catalyzed C-H activation is an important tool for molecular assembly, enabling efficient assembly of complex structures. Ruthenium catalysis offers cost-effective and mild C-H functionalization with unique reactivity, contributing to sustainability in industrial settings. Sustainable ruthenium-catalyzed C-H activation can be achieved using water as a reaction medium.
Catalyzed C-H activation has surfaced as an enabling tool for molecular assembly, with a plethora of translational applications. The enormous developments toward the utilization of ubiquitous C-H bonds as latent functionalities has thus enabled the efficient assembly of increasingly complex scaffolds. Recently, a paradigm shift has occurred to enable sustainable, industry-relevant C-H functionalization manifolds. Among the most prominent transition metals for C-H activations, ruthenium offers several salient features, including cost-effective, robust, and mild C-H activations with unique reactivities for remote functionalization. Indeed, ruthenium(II) catalysis by carboxylate assistance offers a highly functional group tolerant and predictable toolbox for directed as well as nondirected C-H functionalizations, with a major impact to improve the sustainability in industrial settings. These assets have allowed the use of nontoxic, nonflammable, and cost-effective H2O as a reaction medium for sustainable ruthenium(II)-catalyzed C-H activations. In this perspective, we summarize the potential of water for sustainable ruthenium(II)-catalyzed C-H activations up to February 2022.
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