Fire Intumescent, High-Temperature Resistant, Mechanically Flexible Graphene Oxide Network for Exceptional Fire Shielding and Ultra-Fast Fire Warning

Article Chemistry, Applied

Serendipity discovery of fire early warning function of chitosan film

Yong Wang et al.

Summary: Transparent chitosan film prepared with NaCl doping shows excellent performance in high temperature/fire warning. Possible electrical conduction and fire alarm mechanisms are suggested.

CARBOHYDRATE POLYMERS (2022)

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Article Engineering, Environmental

Facile and green fabrication of flame-retardant Ti3C2Tx MXene networks for ultrafast, reusable and weather-resistant fire warning

Min Mao et al.

Summary: This study presents a method for preparing naturally fire-resistant MXene networks with ultrafast fire warning response and recovery time, as well as stable fire cyclic warning capability, and provide reusable and weather-resistant fire warning responses.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

A reactive copper-organophosphate-MXene heterostructure enabled antibacterial, self-extinguishing and mechanically robust polymer nanocomposites

Lei Liu et al.

Summary: The ongoing Covid-19 pandemic has highlighted the urgent need for antibacterial properties in commercially important polymers, such as Epoxy resins, which face challenges of flammability and poor impact toughness. This study presents a reactive multifunctional heterostructure, CuP-MXene, achieving high antibacterial efficiency, flame retardancy, and improved mechanical properties in EP nanocomposites. The synergistic effects between CuP and MXene provide a general strategy for designing multifunctional nanoadditives and advanced polymers with more industrial applications for EP.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Bio-inspired, sustainable and mechanically robust graphene oxide-based hybrid networks for efficient fire protection and warning

Cheng-Fei Cao et al.

Summary: This study presents a new route for the design and development of environmentally friendly fireproof and fire alarm materials based on the effective utilization of natural biomass-derivatives. By constructing synergistic interactions among graphene oxide nanosheets, phosphorylated-cellulose nanofibrils, and tannic acid molecules, a hybrid interconnected network with a hierarchical nacre-like structure was achieved. It exhibited improved mechanical properties, good structural stability, excellent flame retardancy, and ultrasensitive fire alarm functions. Furthermore, this network can act as an effective flame-retardant nanocoating to significantly improve the flame retardancy of combustible PU foam materials.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

B-N-P-linked covalent organic frameworks for efficient flame retarding and toxic smoke suppression of polyacrylonitrile composite fiber

Hongyun Peng et al.

Summary: A novel boron-nitrogen-phosphorus-linked COFs (BNPC) was developed and employed as flame-retardant filler for PAN fiber, significantly reducing peak heat release rate, total smoke production, and CO production. The BNPC also improved the limiting oxygen index value and offered a cooperative catalytic effect for producing a highly compact and crosslinked char layer barrier. This research provides a scalable strategy for designing COFs with multiple flame retardant elements and shows great application potential in functional polymer materials.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Materials Science, Multidisciplinary

Surface decoration of Halloysite nanotubes with POSS for fire-safe thermoplastic polyurethane nanocomposites

Wei Wu et al.

Summary: In this study, POSS containing amino group was covalently grafted on the surface of HNTs, leading to the uniform dispersion of modified HNTs in TPU matrix and significantly improved tensile properties and fire safety of TPU nanocomposites. The addition of HNTs-POSS effectively reduced heat release rate and smoke release, forming a continuous and compact char layer that hindered heat diffusion and evaporation of volatile gases, ultimately enhancing the fire safety of TPU nanocomposites.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

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Article Polymer Science

Graphene oxide/chitosan nano-coating with ultrafast fire-alarm response and flame-retardant property

Fangzhou Yang et al.

Summary: By using layer-by-layer self-assembly technology, an intelligent nano-coating was constructed on melamine foam, which significantly improved the flame retardancy and thermal stability of the material. The nano-coating also enabled super-fast fire response with a continuous alarm time of up to 1280 seconds. This study provides a novel idea for the application of bio-based nano-coating in fire early response and warning systems.

POLYMERS FOR ADVANCED TECHNOLOGIES (2022)

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Article Engineering, Environmental

A flame retardant fabric nanocoating based on nanocarbon black particles@polymer composite and its fire-alarm application

Long Xia et al.

Summary: In this study, a low-cost and high-strength fire-warning sensor CB@KF-CF was successfully fabricated. The sensor demonstrated temperature sensing, fire-warning, flexibility, and high strength. The flame retardant coating, consisting of PVA, CB@KF, and CNT, significantly enhanced the flame retardancy and fire-warning properties of CB@KF-CF, reducing the alarm time to abnormal high temperature and fire.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Highly-sensitive fire alarm system based on cellulose paper with low-temperature response and wireless signal conversion

Xiaolu Li et al.

Summary: This study presents the design of a highly sensitive fire alarm using flame-retardant cellulose paper, graphene oxide (GO), and two-dimensional titanium carbide (Ti3C2, MXene). The fire alarm can detect fire incidents quickly and wirelessly transmit warning signals.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

An OFF-to-ON shape memory polymer conductor for early fire disaster alarming

Jichen Jia et al.

Summary: The casualties and damages caused by wildfires can be avoided if high temperature signals are detected early and prompt rescue actions are taken. In this study, a smart conductor with the ability to switch between conductive and non-conductive states at different temperatures was developed. Outdoor experiments and finite element analysis simulations showed its effectiveness in early fire alarming.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Facile and green synthesis of mechanically fl exible and fl ame-retardant clay/graphene oxide nanoribbon interconnected networks for fi re safety and prevention

Zhi-Ran Yu et al.

Summary: Water-based hybrid graphene oxide nanoribbon/montmorillonite/polyethylene glycol networks were prepared with multiple interactions and high orientation. These networks exhibit synergistic reinforcing and toughening efficiencies, excellent flame resistance, and structural stability, making them promising for widespread application as protective coatings.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Dynamic Nanoconfinement Enabled Highly Stretchable and Supratough Polymeric Materials with Desirable Healability and Biocompatibility

Lei Liu et al.

Summary: The concept of dynamic hydrogen-bonded nanoconfinement is proposed for the first time, leading to the successful design of highly stretchable and supratough biocompatible PVA. This work opens up new opportunities for creating mechanically robust, healable, and biocompatible polymeric materials.

ADVANCED MATERIALS (2021)

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Article Engineering, Manufacturing

Mechanically flexible, super-hydrophobic and flame-retardant hybrid nano-silica/graphene oxide wide ribbon decorated sponges for efficient oil/water separation and fire warning response

Min Mao et al.

Summary: A mechanically flexible, superhydrophobic, and flame-retardant functionalized silica/graphene oxide wide ribbon coated melamine sponge has been developed, showing excellent absorption capacity for oils, efficient oil/water separation performance, and high flame resistance. The material also exhibits fast danger alarm response and stable fire early warning signal in high temperature environments, making it suitable for constructing fire warning sensors.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2021)

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Article Engineering, Environmental

Functionalizing MXene towards highly stretchable, ultratough, fatigue- and fire-resistant polymer nanocomposites

Lei Liu et al.

Summary: This study introduces a hybridized fire retardant (Zr-MXene) strategy, which successfully enhances the mechanical properties of TPU nanocomposites to a record-breaking level while significantly reducing flammability.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Multidisciplinary

Flame-retardant shape memory polyurethane/MXene paper and the application for early fire alarm sensor

Lei Zhang et al.

Summary: This study introduces a flame-retardant paper with shape memory characteristics and self-cutting performance, which can provide stable detection signals and ideal early fire warning responses when exposed to flames.

COMPOSITES PART B-ENGINEERING (2021)

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Article Engineering, Environmental

Engineering MXene surface with POSS for reducing fire hazards of polystyrene with enhanced thermal stability

Bin Yu et al.

Summary: A facile strategy was reported for surface manipulation of Ti3C2Tx with AP-POSS, resulting in POSS-Ti3C2Tx that showed significantly improved thermal and flame retardant properties when incorporated into PS nanocomposites. The outstanding fire safety was attributed to the combination of adsorption, catalytic and barrier effects of POSS-Ti3C2Tx, making it attractive for wide potential applications.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Physical

Skin-inspired thermoelectric nanocoating for temperature sensing and fire safety

Huali Xie et al.

Summary: Inspired by human skin, a thermoelectric flame retardant nanocoating with temperature sensing and fire safety functions was developed, showing accurate temperature sensing and fire-warning capability at high temperatures. The nanocoating exhibited outstanding flame retardancy and self-extinguishing properties, presenting an enticing prospect in the fields of fire protection, electronic skin, and temperature monitor.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Physical

A Durable, Flexible, Large-Area, Flame-Retardant, Early Fire Warning Sensor with Built-In Patterned Electrodes

Fawad Khan et al.

Summary: This study demonstrates the fabrication of a durable, flexible, and large-scale early fire-warning sensor through constructing a hierarchical flame retardant nanocoating on cotton fabric. The sensor shows a short alarming time in response to external high temperature, heat, or fire, and possesses high washability, flexibility, resistance to abrasion and wear. The hierarchical nanocoating can self-extinguish, enabling the sensor to continue warning during fire, thus offering an inventive concept for developing a universal and large-scale very early fire-monitoring platform.

SMALL METHODS (2021)

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Article Engineering, Environmental

Nacre-like graphene oxide paper bonded with boric acid for fire early-warning sensor

Bihe Yuan et al.

Summary: Boric acid-modified graphene oxide (GO-BA) paper, constructed with a nacre structure, shows improved thermal-oxidative stability and can rapidly thermally reduce to conductive reduced graphene oxide under flame exposure, providing a quick flame-detection time for ideal fire-alarm response.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Multidisciplinary

A Hydrophobic Sisal Cellulose Microcrystal Film for Fire Alarm Sensors

Zuocai Zhang et al.

Summary: A simple and green approach has been reported for the development of a hydrophobic, flame-retardant composite film using soy protein isolate, sisal cellulose microcrystals, graphene nanosheets, and citric acid with synergetic benefit. Compared to other composite films, the newly developed film shows significantly improved water resistance and can maintain excellent physical structure and good electrical conductivity in an ethanol flame. This work paves the way for novel fire-retardant fire alarm biosensors.

NANO LETTERS (2021)

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Article Polymer Science

Thermally induced fire early warning aerogel with efficient thermal isolation and flame-retardant properties

Chengran Cao et al.

Summary: This study utilized cellulose nanofiber-based aerogel doped with ammonium polyphosphate and graphene oxide to achieve excellent thermal-insulating and flame-retardant properties. A fire-warning detector was designed to provide the composite aerogel with an ultra-fast fire-response time and durable alarm signal.

POLYMERS FOR ADVANCED TECHNOLOGIES (2021)

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Article Nanoscience & Nanotechnology

Multifunctional MXene/Chitosan-Coated Cotton Fabric for Intelligent Fire Protection

Binglin Wang et al.

Summary: The MXene/CCS@CF cotton fabric developed in this study demonstrated accurate temperature sensing, excellent fire safety performance, and diverse human motion detection capabilities, along with controllable Joule heating performance for extreme cold weather conditions.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Physical

Facile Construction of a Flexible Film with Ultrahigh Thermal Conductivity and Excellent Flame Retardancy for a Smart Fire Alarm

Zhencai Qu et al.

Summary: In this study, a covalently bonded film combining aminated black phosphorene and graphene oxide was developed, showcasing high thermal conductivity, significant flame retardancy, and reduced interface thermal resistance. The flexible film exhibited fast fire alarm response capabilities and continued to function even after exposure to flames, suggesting a new approach for enhancing fire prevention in smart alarm devices.

CHEMISTRY OF MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Bioinspired, Highly Adhesive, Nanostructured Polymeric Coatings for Superhydrophobic Fire-Extinguishing Thermal Insulation Foam

Zhewen Ma et al.

Summary: This study presents a biomimetic strategy to design a polymeric coating with strong adhesion and flame-retardant properties, which can self-extinguish during vertical burning and release low heat and smoke, outperforming previous products.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Electro-Blown Spun Silk/Graphene Nanoionotronic Skin for Multifunctional Fire Protection and Alarm

Leitao Cao et al.

Summary: A flame-retardant silk/graphene nanoionotronic (SGNI) skin with various advantages such as flame retardancy, conductivity, high elasticity, and self-adhesiveness was developed in this study. It can be used in fire alarm systems and potentially offers solutions for the design of protective skins for robotics and human-machine interactions.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

Temperature-Responsive Intumescent Chemistry toward Fire Resistance and Super Thermal Insulation under Extremely Harsh Conditions

Ting Wang et al.

Summary: This study presents a smart temperature-responsive self-intumescent strategy for organic aerogels, which can rapidly form stable porous carbon at high temperatures to achieve excellent fire resistance and high-temperature thermal insulation. The aerogel can expand in real time in response to temperature/fire, resisting various heat conditions and exhibiting the best high-temperature insulating performance ever reported.

CHEMISTRY OF MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Temperature-induced resistance transition behaviors of melamine sponge composites wrapped with different graphene oxide derivatives

Cheng-Fei Cao et al.

Summary: The temperature-responsive resistance transition behaviors of melamine sponges wrapped with different graphene oxide derivatives were investigated, showing different response times to high temperature and flame. This study provides insight into the design and development of smart fire alarm devices for potential fire prevention and safety applications.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Article Engineering, Environmental

A sandwich-like flame retardant nanocoating for supersensitive fire-warning

Huali Xie et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Thermal-triggered insulating fireproof layers: A novel fire-extinguishing MXene composites coating

Yubin Huang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Materials Science, Multidisciplinary

Reconstruction of Grenfell Tower fire. Part 3-Numerical simulation of the Grenfell Tower disaster: Contribution to the understanding of the fire propagation and behaviour during the vertical fire spread

Eric Guillaume et al.

FIRE AND MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Self-Powered and Green Ionic-Type Thermoelectric Paper Chips for Early Fire Alarming

Xun Wu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Environmental

Surface coated rigid polyurethane foam with durable flame retardancy and improved mechanical property

Shuheng Wang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Temperature-responsive resistance sensitivity controlled by L-ascorbic acid and silane co-functionalization in flame-retardant GO network for efficient fire early-warning response

Zhao-Hui Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Manufacturing

Simultaneous improvements in fire resistance and alarm response of GO paper via one-step 3-mercaptopropyltrimethoxysilane functionalization for efficient fire safety and prevention

Neng-Jian Huang et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2020)

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Article Engineering, Electrical & Electronic

Inhibited combustion of graphene paper by in situ phosphorus doping and its application for fire early-warning sensor

Gongqing Chen et al.

SENSORS AND ACTUATORS A-PHYSICAL (2020)

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Article Engineering, Environmental

One-step and green synthesis of lightweight, mechanically flexible and flame-retardant polydimethylsiloxane foam nanocomposites via surface-assembling ultralow content of graphene derivative

Cheng-Fei Cao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Chemo- and Regioselective Additions of Nucleophiles to Cyclic Carbonates for the Preparation of Self-Blowing Non-Isocyanate Polyurethane Foams

Florent Monie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Engineering, Multidisciplinary

Water-based hybrid coatings toward mechanically flexible, super-hydrophobic and flame-retardant polyurethane foam nanocomposites with high-efficiency and reliable fire alarm response

Kun-Yu Guo et al.

COMPOSITES PART B-ENGINEERING (2020)

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Article Chemistry, Physical

Self-powered forest fire alarm system based on impedance matching effect between triboelectric nanogenerator and thermosensitive sensor

Wenquan Liu et al.

NANO ENERGY (2020)

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Article Materials Science, Multidisciplinary

Reconstruction of the Grenfell Tower fire - Part 4: Contribution to the understanding of fire propagation and behaviour during horizontal fire spread

Eric Guillaume et al.

FIRE AND MATERIALS (2020)

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Article Chemistry, Physical

Nacre-biomimetic graphene oxide paper intercalated by phytic acid and its ultrafast fire-alarm application

Gongqing Chen et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Engineering, Environmental

An ultrasensitive fire-warning chitosan/montmorillonite/carbon nanotube composite aerogel with high fire-resistance

Jiayun Chen et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Interface engineering of MXene towards super-tough and strong polymer nanocomposites with high ductility and excellent fire safety

Yongqian Shi et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Materials Science, Composites

A Flame Retardant Rigid Polyurethane Foam System Including Functionalized Graphene Oxide

Ming Gao et al.

POLYMER COMPOSITES (2019)

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Article Engineering, Multidisciplinary

Silane grafted graphene oxide papers for improved flame resistance and fast fire alarm response

Neng-Jian Huang et al.

COMPOSITES PART B-ENGINEERING (2019)

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Article Materials Science, Composites

Design of mechanically stable, electrically conductive and highly hydrophobic three-dimensional graphene nanoribbon composites by modulating the interconnected network on polymer foam skeleton

Cheng-Fei Cao et al.

COMPOSITES SCIENCE AND TECHNOLOGY (2019)

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Article Engineering, Environmental

Temperature-triggered sensitive resistance transition of graphene oxide wide-ribbons wrapped sponge for fire ultrafast detecting and early warning

Hui Xu et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

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Article Materials Science, Multidisciplinary

An eco-friendly non-isocyanate polyurethane treated by CO2 as flame retardant nanocomposite coating/ZrO2@SiO2

M. E. Farid et al.

MATERIALS RESEARCH EXPRESS (2019)

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Article Polymer Science

Properties of a novel inherently flame-retardant rigid polyurethane foam composite bearing imide and oxazolidinone

Daikun Jia et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Bioinspired Color Changing Molecular Sensor toward Early Fire Detection Based on Transformation of Phthalonitrile to Phthalocyanine

Teng Fu et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Polymer Science

Influence of the Characteristics of Expandable Graphite on the Morphology, Thermal Properties, Fire Behaviour and Compression Performance of a Rigid Polyurethane Foam

Pablo Acuna et al.

POLYMERS (2019)

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Article Materials Science, Multidisciplinary

Flame-Retardant Polyurethane Foams: One-Pot, Bioinspired Silica Nanoparticle Coating

Daniel J. Brannum et al.

ACS APPLIED POLYMER MATERIALS (2019)

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Article Chemistry, Applied

Polyphenol-induced cellulose nanofibrils anchored graphene oxide as nanohybrids for strong yet tough soy protein nanocomposites

Zhong Wang et al.

CARBOHYDRATE POLYMERS (2018)

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Article Nanoscience & Nanotechnology

Non-covalently Functionalized Graphene Oxide-Based Coating to Enhance Thermal Stability and Flame Retardancy of PVA Film

Wenhua Chen et al.

NANO-MICRO LETTERS (2018)

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Article Nanoscience & Nanotechnology

Non-covalently Functionalized Graphene Oxide-Based Coating to Enhance Thermal Stability and Flame Retardancy of PVA Film

Wenhua Chen et al.

NANO-MICRO LETTERS (2018)

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Article Polymer Science

Inherently flame-retardant rigid polyurethane foams with excellent thermal insulation and mechanical properties

Shui-Xiu Wang et al.

POLYMER (2018)

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Article Chemistry, Multidisciplinary

Efficient Flame Detection and Early Warning Sensors on Combustible Materials Using Hierarchical Graphene Oxide/Silicone Coatings

Qian Wu et al.

ACS NANO (2018)

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Article Chemistry, Physical

Super-tough artificial nacre based on graphene oxide via synergistic interface interactions of π-π stacking and hydrogen bonding

Pingan Song et al.

CARBON (2017)

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Article Engineering, Multidisciplinary

Analysis of the Response of Smoke Detectors to Smoldering Fires and Nuisance Sources

James Milke et al.

FIRE TECHNOLOGY (2016)

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Article Nanoscience & Nanotechnology

Highly Efficient Flame Retardant Polyurethane Foam with Alginate/Clay Aerogel Coating

Hong-Bing Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Chemistry, Multidisciplinary

Scalable Preparation of Multifunctional Fire-Retardant Ultralight Graphene Foams

Chuangang Hu et al.

ACS NANO (2016)

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Article Chemistry, Multidisciplinary

A Large-Area, Flexible, and Flame-Retardant Graphene Paper

Liye Dong et al.

ADVANCED FUNCTIONAL MATERIALS (2016)

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Article Engineering, Manufacturing

Functionalizing graphene decorated with phosphorus-nitrogen containing dendrimer for high-performance polymer nanocomposites

Yanxian Jin et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2016)

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Article Chemistry, Multidisciplinary

One-pot Synthesis of Nitrogen and Phosphorus Co-doped Graphene and Its Use as High-performance Electrocatalyst for Oxygen Reduction Reaction

Liye Dong et al.

CHEMISTRY-AN ASIAN JOURNAL (2015)

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Article Polymer Science

Research on highly flame-retardant rigid PU foams by combination of nanostructured additives and phosphorus flame retardants

Wei Xu et al.

POLYMER DEGRADATION AND STABILITY (2015)

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Article Multidisciplinary Sciences

Warning signals for eruptive events in spreading fires

Jerome M. Fox et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2015)

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Article Nanoscience & Nanotechnology

Rapid Growing Clay Coatings to Reduce the Fire Threat of Furniture

Yeon Seok Kim et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Review Multidisciplinary Sciences

Fire in the Earth System

David M. J. S. Bowman et al.

SCIENCE (2009)

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Fire Intumescent, High-Temperature Resistant, Mechanically Flexible Graphene Oxide Network for Exceptional Fire Shielding and Ultra-Fast Fire Warning

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