4.6 Article

Research on Flocculant Selection for Classified Fine Tailings Based on Micro-Characterization of Floc Structure Characteristics

期刊

MATERIALS
卷 15, 期 7, 页码 -

出版社

MDPI
DOI: 10.3390/ma15072460

关键词

classified fine tailings; flocculation and sedimentation; nuclear magnetic resonance; SEM image; gray value

资金

  1. National Natural Science Foundation of China [52004019]
  2. National Key Research and Development Program of China [2018YFC0604602]

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This study analyzes the flocculation effect and structure characteristics of different flocculants on classified fine tailings through experiments and observations. The results show that the ZYZ-type flocculant has the best flocculation effect, with a unit consumption of 30 g/t.
The rapid settlement of tailings is an important technical guarantee for the continuous production of downhole filling. The selection of a reasonable flocculant is essential for accelerating the settlement speed of classified fine tailings. The present paper conducts indoor static sedimentation experiments, NMR observation, electron microscope scanning, and other methods to analyze the porosity and pore-size distribution characteristics of floc solution for classified fine tailing under four flocculants, namely, ZYZ, ZYD, JYC-1, and JYC-2. The dimension, spatial distribution characteristics, particle size characteristics, and morphological characteristics of the scanning electron microscope images of floc were studied. Results show that the unit consumption of flocculant at 30 g/t is the critical value for increasing the flocculation and sedimentation effect of the classified fine tailings solution. The highest distribution percentage of small-sized classified fine tailings and the lowest average pore size was observed under the ZYZ-type flocculant. This flocculant also obtained the lowest porosity, largest average floc size, largest area occupied by the floc, lowest pore percentage, and the densest floc structure. Thus, this flocculant showed the best flocculation effect. A negative correlation was observed between the equivalent diameter of floc with varying settlement heights. The dimension of floc increased with the decrease in bed settlement height, and the overall structure of the floc gradually transitioned from loose to dense from top to bottom. The present paper characterizes the microscopic morphology and spatial structure characteristics of floc under different flocculants from a microscopic point of view. The present paper also provides a scientific basis for the selection of the optimal flocculant.

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